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- W2802528181 abstract "Treatment of [{C4H2N-2,5-(CH2PPh2)2-κ3PNP}NiX] (X = Cl (1a), Br (1b), and I (1c)) with the silver salt AgBF4 containing the weakly coordinating anion BF4− yielded two types of complexes: monohalide ion bridged cationic binuclear silver(I) complexes, [Ag2(μ-X){μ-C4H2NH-2,5-(CH2PPh2)2-κ2PP}2][BF4] [X = Cl (2a) and Br (2b)] and the dihalide ions bridged neutral binuclear silver(I) complex, [Ag(μ-I){μ-C4H2NH-2,5-(CH2PPh2)2-κ2PP}]2 (3c). The analogous reaction with AgOTF afforded complex [Ag2(μ-Cl){μ-C4H2NH-2,5-(CH2PPh2)2-κ2PP}2]OTf (2a′). Interestingly, the 31P NMR spectrum of the reaction mixture showed the formation of the cationic complex, [Ni(NCCH3){C4H2N-2,5-(CH2PPh2)2-κ3PNP}][BF4], at the beginning of the reaction, which slowly changes to give the binuclear silver(I) complexes containing the neutral PNP pincer ligand upon crystallization in open atmosphere. Interestingly, the nickel complex 1a reacts with AgSCN containing the coordinating anion SCN− to give both the chlorine-substituted N-bonded thiocyanate neutral complex [Ni(NCS){C4H2N-2,5-(CH2PPh2)2-κ3PNP}] (4) and the dichloride bridged complex [Ag(μ-Cl){μ-C4H2NH-2,5-(CH2PPh2)2-κ2PP}]2 (3a). The structures of all these complexes were determined by single crystal X-ray diffraction studies. The Ni-NNCS bond distance of 1.849(3) Å in 4 is considerably shorter than those reported in the literature." @default.
- W2802528181 created "2018-05-17" @default.
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- W2802528181 date "2018-08-01" @default.
- W2802528181 modified "2023-09-27" @default.
- W2802528181 title "The ‘reverse transmetalation’ reaction of the pyrrole-based PNP pincer Ni(II) complexes: X-ray structures of binuclear silver(I) and thiocyanate nickel(II) complexes" @default.
- W2802528181 cites W1757693970 @default.
- W2802528181 cites W1969009463 @default.
- W2802528181 cites W1972812591 @default.
- W2802528181 cites W1977178597 @default.
- W2802528181 cites W1978890358 @default.
- W2802528181 cites W1980572232 @default.
- W2802528181 cites W1982100202 @default.
- W2802528181 cites W1982229353 @default.
- W2802528181 cites W1989815479 @default.
- W2802528181 cites W1995400296 @default.
- W2802528181 cites W2003459647 @default.
- W2802528181 cites W2005877813 @default.
- W2802528181 cites W2006863900 @default.
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- W2802528181 cites W2010379712 @default.
- W2802528181 cites W2010763248 @default.
- W2802528181 cites W2012056478 @default.
- W2802528181 cites W2013136690 @default.
- W2802528181 cites W2024122111 @default.
- W2802528181 cites W2026003026 @default.
- W2802528181 cites W2030153830 @default.
- W2802528181 cites W2031757629 @default.
- W2802528181 cites W2034707088 @default.
- W2802528181 cites W2046630863 @default.
- W2802528181 cites W2053011214 @default.
- W2802528181 cites W2056393757 @default.
- W2802528181 cites W2058479841 @default.
- W2802528181 cites W2059205366 @default.
- W2802528181 cites W2067722959 @default.
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- W2802528181 doi "https://doi.org/10.1016/j.ica.2018.05.004" @default.
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