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• W2802593291 abstract "Seleno-carbohydrates are those in which the oxygen of the glycosidic bond or the hydroxyl group is artificially replaced with selenium. This substitution changes 1 H and 13 C chemical shifts and produces spin coupling constants involving 77 Se. Coupling constants, such as 2-3 J(77 Se, 1 H), are likely to be useful for conformational analyses of glycans because such couplings are never observed in natural glycans. Several papers have discussed the relationship between 2-3 J(77 Se, 1 H) and conformation; however, only few reports describe 1-3 J(77 Se, 13 C), which could also be useful. Here, we obtain 77 Se coupling constants of seleno-carbohydrates from 77 Se-selective HR-HMBC and 77 Se satellites in 1D 13 C spectra and examine their conformations using the Newman projection scheme." @default.
• W2802593291 created "2018-05-17" @default.
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• W2802593291 date "2018-05-21" @default.
• W2802593291 modified "2023-10-12" @default.
• W2802593291 title "J(77Se,1H) andJ(77Se,13C) couplings of seleno-carbohydrates obtained by77Se satellite 1D13C spectroscopy and77Se selective HR-HMBC spectroscopy" @default.
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• W2802593291 doi "https://doi.org/10.1002/mrc.4746" @default.
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