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- W2802764660 abstract "Four new Cu(II) complexes and one Zn(II) complex of the formula {Cu(salChx)}2n⋅nCH3OH, [Cu(salChx)(imidazole)], [Cu(salChx)(pyrazole)], [Zn2(μ-salChx)2(CH3OH)2] and [Cu2(μ-MeOsalChx)(MeOsalChx)(H2O)2]4⋅3H2O (where salChx is dianion of Schiff-base ligand obtained by condensation of salicylaldehyde with 1-aminocyclohexane-1-carboxylic acid and MeOsalChx is dianion of Schiff-base ligand obtained by condensation of 3-methoxysalicylaldehyde with 1-aminocyclohexane-1-carboxylic acid) have been synthesized and crystallographically fully characterised. Four different geometrical isomers [Cu2(μ-MeOsalChx)(MeOsalChx)(H2O)2] constitute the latest coordination compound together with three crystalline water molecules. They represent a new type of geometrical isomerism in coordination chemistry. Antimicrobial and antiradical activities of all five complexes were assayed." @default.
- W2802764660 created "2018-05-17" @default.
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- W2802764660 date "2018-08-01" @default.
- W2802764660 modified "2023-09-26" @default.
- W2802764660 title "Synthesis, structures and biological activity of copper(II) and zinc(II) Schiff base complexes derived from aminocyclohexane-1-carboxylic acid. New type of geometrical isomerism in polynuclear complexes" @default.
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- W2802764660 doi "https://doi.org/10.1016/j.ica.2018.04.058" @default.
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