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- W2802860003 abstract "A series of Cu(II) complexes supported by methylthiophenyl- and methylfuryl-based (R,R)-1,2-diaminocyclohexane frameworks were synthesised. The synthesised complexes were characterised using infrared spectroscopy, elemental analysis, and single-crystal X-ray diffraction studies. The isopropoxide derivatives of the complexes were employed in the ring-opening polymerisation (ROP) of rac-lactide (rac-LA), yielding polylactides with high number-averaged molecular weight. The catalytic species in this study effectively mediated the stereoselective ROP of rac-LA in a physiological manner (Pr up to 0.92 at room temperature), with ROP activity being mainly dependent on steric hindrance and geometric constraints imposed by methyl substituents attached to the methylthiophenyl and methylfuryl ligands." @default.
- W2802860003 created "2018-05-17" @default.
- W2802860003 creator A5004560620 @default.
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- W2802860003 date "2018-08-01" @default.
- W2802860003 modified "2023-10-14" @default.
- W2802860003 title "Synthesis and structural characterisation of copper complexes containing methylthiophene and methylfuryl derivatives of (R,R)-1,2-diaminocyclohexane as precatalysts for polymerisation of rac-lactide" @default.
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- W2802860003 doi "https://doi.org/10.1016/j.ica.2018.04.025" @default.
- W2802860003 hasPublicationYear "2018" @default.
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