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• W2802925103 abstract "A concise method of constructing polycyclic tropinone frameworks was developed. The single-step synthesis of polycyclic tropinone consists of an intramolecular [4+3] cycloaddition reaction of N-nosyl-pyrrole with oxyallyl cation that was generated in situ by an intermolecular condensation reaction of the nucleophilic functional groups on a tethered pyrrole with the aldehyde of 2-(silyloxy)-acrolein. This cascade reaction afforded various polycyclic tropinones including tri-, tetra-, and pentacyclic systems in high yields as single diastereomers." @default.
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• W2802925103 date "2018-06-10" @default.
• W2802925103 modified "2023-09-24" @default.
• W2802925103 title "Direct Synthesis of Polycyclic Tropinones by a Condensation-[4+3]-Cycloaddition Cascade Reaction" @default.
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• W2802925103 doi "https://doi.org/10.1002/chem.201802011" @default.
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