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- W2802961036 abstract "Vaporisation studies on U-19 wt%Pu-6wt%Zr alloy were carried out by using a high temperature mass spectrometry. Pu(g) was the vapour species observed over the alloy. The pressure – temperature relations were derived over (solid + liquid) two phase and liquid phase regions in the temperature ranges 1481–1623 K and 1661–1773 K, respectively. The corresponding vapour pressure equations were found to be as log(ppu/Pa) = (−22254 ± 282)/T+(10.80 ± 0.18) and log(ppu/Pa) = (−22021 ± 1169)/T+(10.52 ± 0.68) respectively. The enthalpies of vaporisation of Pu(g) over these phase regions were deduced. The vapour pressure of Pu(g) over the U-Pu-Zr alloy and its enthalpy of vaporisation data have been obtained for the first time. The data obtained were compared with those obtained by computations based on experimental data on U-Zr and Pu-Zr binaries and ideal solution model." @default.
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- W2802961036 date "2018-08-01" @default.
- W2802961036 modified "2023-09-24" @default.
- W2802961036 title "Mass spectrometric studies on U-Pu-Zr alloy" @default.
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- W2802961036 doi "https://doi.org/10.1016/j.jnucmat.2018.05.020" @default.
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