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• W2803145732 abstract "LTO (Li4Ti5O12) has been highlighted as anode material for next-generation lithium ion secondary batteries due to advantages such as a high rate capability, excellent cyclic performance, and safety. However, the generation of gases from undesired reactions between the electrode surface and the electrolyte has restricted the application of LTO as a negative electrode in Li-ion batteries in electric vehicles (EVs) and energy storage systems (ESS). As the generation of gases from LTO tends to be accelerated at high temperatures (40–60 °C), the thermal stability of LTO should be maintained during battery discharge, especially in EVs. To overcome these technical limitations, a thin layer of Al2O3 (~2 nm thickness) was deposited on the LTO electrode surface by atomic layer deposition (ALD), and an electrochemical charge-discharge cycle test was performed at 60 °C. The capacity retention after 500 cycles clearly shows that Al2O3-coated LTO outperforms the uncoated one, with a discharge capacity retention of ~98%. TEM and XPS analyses indicate that the surface reactions of Al2O3-coated LTO are suppressed, while uncoated LTO undergoes the (111) to (222) phase transformation, as previously reported in the literature." @default.
• W2803145732 created "2018-06-01" @default.
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• W2803145732 date "2018-05-16" @default.
• W2803145732 modified "2023-10-06" @default.
• W2803145732 title "Highly-Stable Li4Ti5O12 Anodes Obtained by Atomic-Layer-Deposited Al2O3" @default.
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• W2803145732 doi "https://doi.org/10.3390/ma11050803" @default.
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• W2803145732 hasPublicationYear "2018" @default.
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