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• W2803394080 abstract "Efficient syntheses of both enantiomers of a spirodiamine diester from (l)- and (d)-aspartic acid are described. The key transformation was the conversion of Boc-protected tert-butyl aspartate into the derived aldehyde, two-directional Horner-Wadsworth-Emmons olefination, hydrogenation, and selective acid-catalyzed Boc-deprotection and spirocyclization. An alternative, two-directional approach to derivatives of 1,7-diazaspiro[5.5]undecane is described." @default.
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• W2803394080 date "2018-05-23" @default.
• W2803394080 modified "2023-10-05" @default.
• W2803394080 title "Bidirectional Synthesis of Di-<i>tert</i>-butyl (2<i>S</i>,6<i>S</i>,8<i>S</i>)- and (2<i>R</i>,6<i>R</i>,8<i>R</i>)-1,7-Diazaspiro[5.5]undecane-2,8-dicarboxylate and Related Spirodiamines" @default.
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• W2803394080 doi "https://doi.org/10.1021/acs.joc.8b00794" @default.
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