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- W2803535779 abstract "Abstract A new dinuclear terbium complex (Tb-complex) is designed and synthesized based on 2,4,5-Trifluoro-3-methoxybenzoic acid (HTFMBA). The exact structure of the Tb-complex is determined to be [Tb2(TFMBA)6(phen)2] (phen = phenanthroline). It crystallizes in the triclinic space group P-1, and it is further characterized by FT-IR, PXRD, EA, TGA and luminescence. Tb-complex shows very high luminescence quantum yield (QY) of 61.5%. Detailed investigation reveals that the Tb-complex is a highly sensitive and selective bifunctional sensor for detecting S O 4 2 − and CH3Hg+. Responsive behavior shows the detection has excellent linear relationship between luminescence and the concentration of S O 4 2 − and CH3Hg+. The limit of detection (LOD) for detecting S O 4 2 − and CH3Hg+ are as low as 5 × 10−7 M and 2.8 × 10−9 M, respectively. This is the first bifunctional sensor that could probe the highly toxic CH3Hg+, and it is the most sensitive chemosensor for detecting CH3Hg+. Further investigation also reveal that the Tb-complex is applicable in sensing S O 4 2 − and highly toxic CH3Hg+ in real water samples." @default.
- W2803535779 created "2018-06-01" @default.
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- W2803535779 date "2018-10-01" @default.
- W2803535779 modified "2023-10-17" @default.
- W2803535779 title "Highly sensitive bifunctional sensor of a dinuclear terbium complex" @default.
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- W2803535779 doi "https://doi.org/10.1016/j.snb.2018.05.073" @default.
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