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- W2803553144 abstract "A novel iterative protocol for the synthesis of polydeoxypropionates was developed based on iridium-catalyzed asymmetric hydrogenation of α-substituted acrylic acids. The catalyst loading can be as low as 0.01 mol %, and the overall yield for one iterative cycle is >76%. The reaction conditions are mild, and no organometallic reagents or chromatography steps are required. Using this protocol, (+)-phthioceranic acid and the polydeoxypropionate motifs of ionomycin and borrelidin were synthesized in high yield." @default.
- W2803553144 created "2018-06-01" @default.
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- W2803553144 date "2018-05-21" @default.
- W2803553144 modified "2023-10-15" @default.
- W2803553144 title "Iterative Synthesis of Polydeoxypropionates Based on Iridium-Catalyzed Asymmetric Hydrogenation of α-Substituted Acrylic Acids" @default.
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- W2803553144 doi "https://doi.org/10.1021/acs.orglett.8b01193" @default.
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