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- W2803559615 abstract "This paper reports a new method for the generation of substituted 1,3-enynes, whose synthesis by other methods could be a challenge. The dehydrative decarboxylative cascade coupling reaction of propargyl alcohol with alkyl peroxides is enabled by an iron catalyst and alkylating reagents. Primary, secondary, and tertiary alkyl groups can be introduced into 1,3-enynes, affording various substituted 1,3-enynes in moderate to good yields. Mechanistic studies suggest the involvement of a radical-polar crossover pathway." @default.
- W2803559615 created "2018-06-01" @default.
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- W2803559615 date "2018-05-22" @default.
- W2803559615 modified "2023-10-16" @default.
- W2803559615 title "Iron-Catalyzed Dehydrative Alkylation of Propargyl Alcohol with Alkyl Peroxides To Form Substituted 1,3-Enynes" @default.
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- W2803559615 doi "https://doi.org/10.1021/acs.orglett.8b01043" @default.
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