Matches in SemOpenAlex for { <https://semopenalex.org/work/W2803611523> ?p ?o ?g. }
- W2803611523 endingPage "852" @default.
- W2803611523 startingPage "846" @default.
- W2803611523 abstract "Compound [Ir(C8H12)(C51H45P4)]Cl2 or [Ir(cod)(CH(dppm)2-κ3P,C,P)]Cl2 (1a), was obtained from [IrCl(cod)]2 and the carbodi-phospho-rane (CDP) salt [CH(dppm)2]Cl [where cod = cyclo-octa-1,5-diene and dppm = bis-(di-phenyl-phosphino)methane]. Treatment of 1a with thallium(I) tri-fluoro-methane-sulfonate [Tl(OTf)] and subsequent crystallization gave complex [Ir(C8H12)(C51H45P4)](OTf)2·CH3CO2C2H5·CH2Cl2 or [Ir(cod)(CH(dppm)2-κ3P,C,P)](OTf)2·CH3CO2C2H5·CH2Cl2 (1b) [systematic name: (cyclo-octa-1,5-diene)(1,1,3,3,5,5,7,7-octa-phenyl-1,7-diphospha-3,5-di-phospho-niaheptan-4-yl)iridium(I) bis-(tri-fluoro-methane-sulfonate)-ethyl acetate-di-chloro-methane (1/1/1)]. This five-coordinate iridium(I) complex cation adopts a trigonal-bipyramidal geometry with the CDP carbon and one cod double bond in axial sites. Compound 1b represents the first example of a non-meridional coordination of the PCP pincer ligand [CH(dppm)2]+ with a P-Ir-P angle of 98.08 (2)°. Compound 2, [IrCl2H(C51H44P4)]·(CH3)2CO or [IrCl2H(C(dppm)2-κ3P,C,P)]·(CH3)2CO [systematic name: di-chlorido-hydrido(1,1,3,3,5,5,7,7-octa-phenyl-1,5λ5,7-triphospha-3-phospho-niahept-4-en-4-yl)iridium(III) acetone monosolvate], crystallizes as an acetone monosolvate. It is a six-coordinate IrIII coordination compound. Here, the PCP pincer ligand is coordinated in a meridional manner; one chlorido ligand is positioned trans to the carbon donor, the remaining two coordination sites being occupied by the second chlorido and a hydrido ligand trans to each other. Complex 3, [IrCl2H(C51H45P4)]Cl·5H2O or [IrCl2H(CH(dppm)2-κ3P,C,P)]Cl·5H2O [systematic name: di-chlorido-hydrido(1,1,3,3,5,5,7,7-octa-phenyl-1,7-diphospha-3,5-di-phospho-niaheptan-4-yl)iridium(III) chloride penta-hydrate], represents the conjugate CH acid of 2. The ligand [CH(dppm)2]+ is coordinated in a meridional manner. In the cationic six-coordinate IrIII complex 4, [IrClH(CO)(C51H44P4)]Cl·2CH3OH·H2O or [IrClH(CO)(C(dppm)2-κ3P,C,P)]Cl·2CH3OH·H2O [systematic name: carbonyl-chlorido-hydrido(1,1,3,3,5,5,7,7-octa-phenyl-1,5λ5,7-triphospha-3-phos-pho-niahept-4-en-4-yl)iridium(III) chloride-methanol-water (1/2/1)], the chlorido ligand is found in the plane defined by the Ir center and the meridional PCP ligand; the H and CO ligands are positioned axially to this plane and trans to each other." @default.
- W2803611523 created "2018-06-01" @default.
- W2803611523 creator A5017143293 @default.
- W2803611523 creator A5022007340 @default.
- W2803611523 creator A5027364443 @default.
- W2803611523 creator A5050814944 @default.
- W2803611523 creator A5059816453 @default.
- W2803611523 creator A5079059750 @default.
- W2803611523 creator A5021693475 @default.
- W2803611523 date "2018-05-25" @default.
- W2803611523 modified "2023-09-24" @default.
- W2803611523 title "Crystal structures of four new iridium complexes, each containing a highly flexible carbodiphosphorane PCP pincer ligand" @default.
- W2803611523 cites W1969360633 @default.
- W2803611523 cites W1979007101 @default.
- W2803611523 cites W1979368277 @default.
- W2803611523 cites W1984234543 @default.
- W2803611523 cites W1990170643 @default.
- W2803611523 cites W2015852082 @default.
- W2803611523 cites W2031158103 @default.
- W2803611523 cites W2078801621 @default.
- W2803611523 cites W2091597188 @default.
- W2803611523 cites W2102514179 @default.
- W2803611523 cites W2131350133 @default.
- W2803611523 cites W2132454074 @default.
- W2803611523 cites W2141893687 @default.
- W2803611523 cites W2171512060 @default.
- W2803611523 cites W2318724094 @default.
- W2803611523 cites W2334264524 @default.
- W2803611523 cites W2335578974 @default.
- W2803611523 cites W2796160267 @default.
- W2803611523 cites W2298744815 @default.
- W2803611523 doi "https://doi.org/10.1107/s2056989018007569" @default.
- W2803611523 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/6002832" @default.
- W2803611523 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/29951243" @default.
- W2803611523 hasPublicationYear "2018" @default.
- W2803611523 type Work @default.
- W2803611523 sameAs 2803611523 @default.
- W2803611523 citedByCount "8" @default.
- W2803611523 countsByYear W28036115232018 @default.
- W2803611523 countsByYear W28036115232019 @default.
- W2803611523 countsByYear W28036115232020 @default.
- W2803611523 countsByYear W28036115232021 @default.
- W2803611523 crossrefType "journal-article" @default.
- W2803611523 hasAuthorship W2803611523A5017143293 @default.
- W2803611523 hasAuthorship W2803611523A5021693475 @default.
- W2803611523 hasAuthorship W2803611523A5022007340 @default.
- W2803611523 hasAuthorship W2803611523A5027364443 @default.
- W2803611523 hasAuthorship W2803611523A5050814944 @default.
- W2803611523 hasAuthorship W2803611523A5059816453 @default.
- W2803611523 hasAuthorship W2803611523A5079059750 @default.
- W2803611523 hasBestOaLocation W28036115231 @default.
- W2803611523 hasConcept C104317684 @default.
- W2803611523 hasConcept C111592845 @default.
- W2803611523 hasConcept C115624301 @default.
- W2803611523 hasConcept C116569031 @default.
- W2803611523 hasConcept C123010829 @default.
- W2803611523 hasConcept C127313418 @default.
- W2803611523 hasConcept C143065580 @default.
- W2803611523 hasConcept C155647269 @default.
- W2803611523 hasConcept C161790260 @default.
- W2803611523 hasConcept C170493617 @default.
- W2803611523 hasConcept C178790620 @default.
- W2803611523 hasConcept C185592680 @default.
- W2803611523 hasConcept C2777961443 @default.
- W2803611523 hasConcept C2778468751 @default.
- W2803611523 hasConcept C3018250846 @default.
- W2803611523 hasConcept C528581852 @default.
- W2803611523 hasConcept C544153396 @default.
- W2803611523 hasConcept C55493867 @default.
- W2803611523 hasConcept C71240020 @default.
- W2803611523 hasConcept C8010536 @default.
- W2803611523 hasConcept C91586092 @default.
- W2803611523 hasConcept C91819851 @default.
- W2803611523 hasConceptScore W2803611523C104317684 @default.
- W2803611523 hasConceptScore W2803611523C111592845 @default.
- W2803611523 hasConceptScore W2803611523C115624301 @default.
- W2803611523 hasConceptScore W2803611523C116569031 @default.
- W2803611523 hasConceptScore W2803611523C123010829 @default.
- W2803611523 hasConceptScore W2803611523C127313418 @default.
- W2803611523 hasConceptScore W2803611523C143065580 @default.
- W2803611523 hasConceptScore W2803611523C155647269 @default.
- W2803611523 hasConceptScore W2803611523C161790260 @default.
- W2803611523 hasConceptScore W2803611523C170493617 @default.
- W2803611523 hasConceptScore W2803611523C178790620 @default.
- W2803611523 hasConceptScore W2803611523C185592680 @default.
- W2803611523 hasConceptScore W2803611523C2777961443 @default.
- W2803611523 hasConceptScore W2803611523C2778468751 @default.
- W2803611523 hasConceptScore W2803611523C3018250846 @default.
- W2803611523 hasConceptScore W2803611523C528581852 @default.
- W2803611523 hasConceptScore W2803611523C544153396 @default.
- W2803611523 hasConceptScore W2803611523C55493867 @default.
- W2803611523 hasConceptScore W2803611523C71240020 @default.
- W2803611523 hasConceptScore W2803611523C8010536 @default.
- W2803611523 hasConceptScore W2803611523C91586092 @default.
- W2803611523 hasConceptScore W2803611523C91819851 @default.
- W2803611523 hasIssue "6" @default.
- W2803611523 hasLocation W28036115231 @default.
- W2803611523 hasLocation W28036115232 @default.