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• W2803674460 endingPage "3361" @default.
• W2803674460 startingPage "3358" @default.
• W2803674460 abstract "Total synthesis of (−)-(2R,9S)- and (+)-(2S,9S)-stereoisomers of laingolide B has been accomplished by using sequential ring-closing metathesis (RCM) and alkene isomerization to construct the macrocyclic trans-N-methyl enamide moiety. The Myers alkylation was used to secure the C2 stereochemistry of the two RCM precursors from a common (9S)-C3–C9 alkyl iodide. The absolute configuration of laingolide B has been assigned as (2S,9R) by comparison of the optical rotation data." @default.
• W2803674460 created "2018-06-01" @default.
• W2803674460 creator A5018641849 @default.
• W2803674460 creator A5060836006 @default.
• W2803674460 date "2018-05-21" @default.
• W2803674460 modified "2023-09-30" @default.
• W2803674460 title "Total Synthesis of Laingolide B Stereoisomers and Assignment of Absolute Configuration" @default.
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• W2803674460 doi "https://doi.org/10.1021/acs.orglett.8b01269" @default.
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