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- W2803687971 abstract "Abstract In this work, three different activated carbons were prepared from low-rank bituminous coal by KOH activation method. High-pressure methane adsorption tests were conducted to these three different activated carbons from 273.15 to 373.15 K. Experimental results show that 313.15 K seems to be the critical temperature point for methane adsorption. When the adsorption temperature is lower than 313.15 K, methane adsorption amount would be rapidly decreased with the increase of temperature. The maximum-monolayer adsorption capacity qm, which is fitted by adsorption experimental result of activated carbon, would be gradually decreased with the increase of temperature. The adsorption equilibrium constant b also presents the similar law as the temperature changes. Thermodynamic parameters show that methane adsorption on activated carbons are nonspontaneous (ΔG° > 0) and exothermic (ΔH°" @default.
- W2803687971 created "2018-06-01" @default.
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- W2803687971 date "2018-10-01" @default.
- W2803687971 modified "2023-10-01" @default.
- W2803687971 title "Thermodynamic analysis of high-pressure methane adsorption on coal-based activated carbon" @default.
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- W2803687971 doi "https://doi.org/10.1016/j.fuel.2018.05.056" @default.
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