Matches in SemOpenAlex for { <https://semopenalex.org/work/W2803712767> ?p ?o ?g. }
- W2803712767 abstract "Abstract Although considerable efforts have been made in converting carbon dioxide to hydrocarbons via hydrogenation processes, precise control of C–C coupling towards heavy olefins remains a challenge. Here we report a carbon dioxide hydrogenation to olefin process that achieves 72% selectivity for alkenes and 50.3% selectivity for C 4–18 alkenes, of which formation of linear α-olefins accounts for 80%. The process is catalyzed by carbon-supported iron, commonly used in C–C coupling reactions, with multiple alkali promoters extracted from corncob. The design is based on the synergistic catalysis of mineral elements in biomass enzyme on which carbon dioxide can be directly converted into carbohydrate. The mineral elements from corncob may promote the surface enrichment of potassium, suppressing the secondary hydrogenation of alkenes on active sites. Furthermore, carburization of iron species is enhanced to form more Fe 5 C 2 species, promoting both the reverse water–gas shift reaction and subsequent C–C coupling." @default.
- W2803712767 created "2018-06-01" @default.
- W2803712767 creator A5020415236 @default.
- W2803712767 creator A5029687574 @default.
- W2803712767 creator A5031509338 @default.
- W2803712767 creator A5042987873 @default.
- W2803712767 creator A5047134204 @default.
- W2803712767 creator A5069856423 @default.
- W2803712767 creator A5072413669 @default.
- W2803712767 creator A5081444687 @default.
- W2803712767 date "2018-03-22" @default.
- W2803712767 modified "2023-10-12" @default.
- W2803712767 title "Directly converting carbon dioxide to linear α-olefins on bio-promoted catalysts" @default.
- W2803712767 cites W1864848383 @default.
- W2803712767 cites W1870760280 @default.
- W2803712767 cites W1969558605 @default.
- W2803712767 cites W1969901083 @default.
- W2803712767 cites W1972198249 @default.
- W2803712767 cites W1973210652 @default.
- W2803712767 cites W1993992090 @default.
- W2803712767 cites W1994113463 @default.
- W2803712767 cites W1995815400 @default.
- W2803712767 cites W2001624882 @default.
- W2803712767 cites W2004934247 @default.
- W2803712767 cites W2005837071 @default.
- W2803712767 cites W2033177740 @default.
- W2803712767 cites W2051596037 @default.
- W2803712767 cites W2051939850 @default.
- W2803712767 cites W2066218922 @default.
- W2803712767 cites W2073065588 @default.
- W2803712767 cites W2078353661 @default.
- W2803712767 cites W2110154495 @default.
- W2803712767 cites W2118025948 @default.
- W2803712767 cites W2119611880 @default.
- W2803712767 cites W2145172842 @default.
- W2803712767 cites W2271681144 @default.
- W2803712767 cites W2477980016 @default.
- W2803712767 cites W2487512096 @default.
- W2803712767 cites W2499525893 @default.
- W2803712767 cites W2524426479 @default.
- W2803712767 cites W2549880953 @default.
- W2803712767 cites W2562802329 @default.
- W2803712767 cites W2592037280 @default.
- W2803712767 cites W2611869399 @default.
- W2803712767 cites W2624906538 @default.
- W2803712767 cites W2763759304 @default.
- W2803712767 cites W2951861141 @default.
- W2803712767 cites W567580503 @default.
- W2803712767 doi "https://doi.org/10.1038/s42004-018-0012-4" @default.
- W2803712767 hasPublicationYear "2018" @default.
- W2803712767 type Work @default.
- W2803712767 sameAs 2803712767 @default.
- W2803712767 citedByCount "114" @default.
- W2803712767 countsByYear W28037127672018 @default.
- W2803712767 countsByYear W28037127672019 @default.
- W2803712767 countsByYear W28037127672020 @default.
- W2803712767 countsByYear W28037127672021 @default.
- W2803712767 countsByYear W28037127672022 @default.
- W2803712767 countsByYear W28037127672023 @default.
- W2803712767 crossrefType "journal-article" @default.
- W2803712767 hasAuthorship W2803712767A5020415236 @default.
- W2803712767 hasAuthorship W2803712767A5029687574 @default.
- W2803712767 hasAuthorship W2803712767A5031509338 @default.
- W2803712767 hasAuthorship W2803712767A5042987873 @default.
- W2803712767 hasAuthorship W2803712767A5047134204 @default.
- W2803712767 hasAuthorship W2803712767A5069856423 @default.
- W2803712767 hasAuthorship W2803712767A5072413669 @default.
- W2803712767 hasAuthorship W2803712767A5081444687 @default.
- W2803712767 hasBestOaLocation W28037127671 @default.
- W2803712767 hasConcept C104779481 @default.
- W2803712767 hasConcept C111368507 @default.
- W2803712767 hasConcept C115540264 @default.
- W2803712767 hasConcept C118792377 @default.
- W2803712767 hasConcept C127313418 @default.
- W2803712767 hasConcept C140205800 @default.
- W2803712767 hasConcept C159985019 @default.
- W2803712767 hasConcept C161790260 @default.
- W2803712767 hasConcept C178790620 @default.
- W2803712767 hasConcept C179104552 @default.
- W2803712767 hasConcept C185592680 @default.
- W2803712767 hasConcept C192562407 @default.
- W2803712767 hasConcept C206139338 @default.
- W2803712767 hasConcept C2778597550 @default.
- W2803712767 hasConcept C2778821838 @default.
- W2803712767 hasConcept C51886252 @default.
- W2803712767 hasConcept C530467964 @default.
- W2803712767 hasConceptScore W2803712767C104779481 @default.
- W2803712767 hasConceptScore W2803712767C111368507 @default.
- W2803712767 hasConceptScore W2803712767C115540264 @default.
- W2803712767 hasConceptScore W2803712767C118792377 @default.
- W2803712767 hasConceptScore W2803712767C127313418 @default.
- W2803712767 hasConceptScore W2803712767C140205800 @default.
- W2803712767 hasConceptScore W2803712767C159985019 @default.
- W2803712767 hasConceptScore W2803712767C161790260 @default.
- W2803712767 hasConceptScore W2803712767C178790620 @default.
- W2803712767 hasConceptScore W2803712767C179104552 @default.
- W2803712767 hasConceptScore W2803712767C185592680 @default.
- W2803712767 hasConceptScore W2803712767C192562407 @default.
- W2803712767 hasConceptScore W2803712767C206139338 @default.
- W2803712767 hasConceptScore W2803712767C2778597550 @default.