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- W2803764502 abstract "In search of magneto-optic materials, the mononuclear compounds LnIII (depma)(NO3 )3 (hmpa)2 (Ln=Dy, Gd) were synthesized. The anthracene moieties undergo [4+4] dimerization when irradiated at 365 nm without loss of crystallinity. The Dy compound switches from a single-ion to a single-molecule magnet with doubling of the spin reversal barrier energy and from yellow-green to blue-white emission. The dimerization is reversed by heating at 100 °C or partially on light irradiating at 254 nm. The results suggest that lanthanide phosphonates with anthracene are promising smart materials displaying synergistic magneto-optic property." @default.
- W2803764502 created "2018-06-01" @default.
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- W2803764502 date "2018-06-14" @default.
- W2803764502 modified "2023-10-04" @default.
- W2803764502 title "Reversible SC‐SC Transformation involving [4+4] Cycloaddition of Anthracene: A Single‐Ion to Single‐Molecule Magnet and Yellow‐Green to Blue‐White Emission" @default.
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- W2803764502 doi "https://doi.org/10.1002/anie.201804102" @default.
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