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- W2803844992 abstract "An efficient and chemodivergent palladium-catalyzed thiolation (C–S) and imidation (C–N) of directing group-assisted C–H bonds have been accomplished employing N-(arylthio)imides in combination with either Brønsted acid or Lewis acid, respectively. Notable features of the developed methodologies include excellent diversity, high functional group tolerance, wide substrate scope, and use of a single N–S reagent. Importantly, the developed hypothesis was also successfully extended to the amidation of C–H bonds. A plausible mechanistic pathway was proposed based on the preliminary mechanistic study." @default.
- W2803844992 created "2018-06-01" @default.
- W2803844992 creator A5058176399 @default.
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- W2803844992 date "2018-05-18" @default.
- W2803844992 modified "2023-10-14" @default.
- W2803844992 title "Lewis Acid/Brønsted Acid Controlled Pd(II)-Catalyzed Chemodivergent Functionalization of C(<i>sp</i><sup>2</sup>)–H Bonds with <i>N</i>-(Arylthio)i(a)mides" @default.
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- W2803844992 doi "https://doi.org/10.1021/acs.orglett.8b01281" @default.
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