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- W2804184377 abstract "Abstract Herein we report the synthesis and photophysical and supramolecular properties of a novel three‐dimensional capsule‐like hexa‐ peri ‐hexabenzocoronene (HBC)‐containing carbon nanocage, tripodal‐[2]HBC, which is the first synthetic model of capped zigzag [12,0] carbon nanotubes (CNTs). Tripodal‐[2]HBC was synthesized by the palladium‐catalyzed coupling of triboryl hexabenzocoronene and L‐shaped cyclohexane units, followed by nickel‐mediated C−Br/C−Br coupling and subsequent aromatization of the cyclohexane moieties. The physical properties of tripodal‐[2]HBC and its supramolecular host–guest interaction with C 70 were further studied by UV/Vis and fluorescence spectroscopy. Theoretical calculations revealed that the strain energy of tripodal‐[2]HBC was as high as 55.2 kcal mol −1 ." @default.
- W2804184377 created "2018-06-01" @default.
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- W2804184377 date "2018-06-25" @default.
- W2804184377 modified "2023-10-16" @default.
- W2804184377 title "A Three-Dimensional Capsule-like Carbon Nanocage as a Segment Model of Capped Zigzag [12,0] Carbon Nanotubes: Synthesis, Characterization, and Complexation with C<sub>70</sub>" @default.
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- W2804184377 doi "https://doi.org/10.1002/anie.201804031" @default.
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