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• W2804201710 startingPage "1095" @default.
• W2804201710 abstract "Streptococcus pneumonia (SPn) is a Gram-positive bacterium which causes life threatening diseases. The bacteria protect themselves against non-specific host defence by an external polysaccharide (PS) capsule which bears a repeating unit, α-D-Galp(1->3)-α-D-Glcp(1->3)-α-L-Rhap(1->3)-D-Rib (SPn 6A). A closer look at the structure reveals the presence of α-linked galactose and glucose residues. The synthesis of these 1,2- cis glycosidic linkages are considered challenging particularly in the context of a one-pot oligosaccharide synthesis. We have synthesized the aforesaid tetrasaccharide (SPn 6A) based on both stepwise and sequential one-pot glycosylation reactions using easily accessible common building blocks; eventually similar overall yields were obtained in both cases." @default.
• W2804201710 created "2018-06-01" @default.
• W2804201710 creator A5024795952 @default.
• W2804201710 creator A5035098731 @default.
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• W2804201710 date "2018-05-17" @default.
• W2804201710 modified "2023-10-01" @default.
• W2804201710 title "Synthetic avenues towards a tetrasaccharide related to <i>Streptococcus pneumonia</i> of serotype 6A" @default.
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• W2804201710 doi "https://doi.org/10.3762/bjoc.14.95" @default.
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