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- W2804353867 abstract "Rare earth fluoride carbonates have been proven to be potential deep-ultraviolet optical materials, but lacked the systematic study on phase stability domains to guide synthesis. In this work, detailed investigations of the Na2CO3–GdF3–H2O system have been done in subcritical hydrothermal conditions. A series of sodium-rare earth carbonates crystals NaGdCO3F2 (1), Na2GdCO3F3 (2), Na3Gd(CO3)3 (3), and Na3Gd(CO3)3·6H2O (4) have been synthesized. NaGdCO3F2 (1) is composed of a three-dimensional (3-D) [GdCO3F2]− framework with Na+ as the charge balance cation. Na2GdCO3F3 (2) showed two-dimensional (2-D) [GdCO3F3]2– layers along the c-axis and further bridged by Na+ to form a 3-D framework. Na3Gd(CO3)3 (3) is made up of alternately stacked layers [Na(CO3)2]∞ along the a-axis and [Na2Gd(CO3)2]∞ in the bc plane, forming a 3-D framework. Na3Gd(CO3)3·6H2O (4) exhibits an intricate 3-D structure composed of a [Gd(CO3)3(H2O)3]3– complex and bridging Na+ ions. The results from the UV–vis diffuse reflectance spectroscopy study indicated that the short-wavelength absorption edge of all four compounds were below 200 nm, suggesting that they are potential deep-ultraviolet optical materials. Powder second harmonic generation measurements indicated that the compounds 3 and 4 are phase-matchable (type I), and they exhibit relatively strong second harmonic generation responses of approximately 3 and 2 times that of KH2PO4 (KDP)." @default.
- W2804353867 created "2018-06-01" @default.
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- W2804353867 date "2018-05-20" @default.
- W2804353867 modified "2023-10-16" @default.
- W2804353867 title "Exploring Potential Beryllium-free, Deep-Ultraviolet Optical Crystals in the Rare Earth Fluoride Carbonate–Water System" @default.
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- W2804353867 doi "https://doi.org/10.1021/acs.cgd.8b00431" @default.
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