FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2804486346> ?p ?o ?g. }

• W2804486346 endingPage "12349" @default.
• W2804486346 startingPage "12341" @default.
• W2804486346 abstract "Understanding the surface (electro)chemistry of CO2 and CO on Pt is needed to design active, selective catalysts for CO-tolerant fuel cell reactions and CO2 reduction. In this work, the surface reactivity of Pt in a CO2-saturated alkaline electrolyte was revealed by combining in situ surface-enhanced infrared absorption spectroscopy (SEIRAS) with density functional theory (DFT) calculations. We show that during potential cycling in 1 M KHCO3 electrolyte, CO adsorbates (COad), more specifically, COad surrounded by OH adsorbates (OHad), with linear or bridged configuration, were produced through the reductive adsorption of HCO3– catalyzed by H adsorbates on Pt. The COad coadsorbed with OHad was oxidized to COOHad at potentials as low as ∼0.3 VRHE, which was further oxidized to CO2 at 0.9 VRHE and higher. Further analysis suggests that the proximity between COad and OHad is key to trigger the conversion reaction from COad to CO2 through forming COOHad intermediate at room temperature. The details about how Pt surface adsorbates change as a function of voltage in CO2-saturated alkaline electrolytes can provide strategies to design CO-tolerant catalysts for fuel cell applications and active and selective catalysts for the CO2 reduction reaction." @default.
• W2804486346 created "2018-06-01" @default.
• W2804486346 creator A5022371820 @default.
• W2804486346 creator A5027366818 @default.
• W2804486346 creator A5044714370 @default.
• W2804486346 creator A5052065929 @default.
• W2804486346 creator A5054988983 @default.
• W2804486346 creator A5059373986 @default.
• W2804486346 creator A5072220519 @default.
• W2804486346 creator A5072645578 @default.
• W2804486346 date "2018-05-23" @default.
• W2804486346 modified "2023-10-16" @default.
• W2804486346 title "Surface (Electro)chemistry of CO₂ on Pt Surface: An <i>in Situ</i> Surface-Enhanced Infrared Absorption Spectroscopy Study" @default.
• W2804486346 cites W103659393 @default.
• W2804486346 cites W1523117260 @default.
• W2804486346 cites W1578842490 @default.
• W2804486346 cites W1598532830 @default.
• W2804486346 cites W1775568493 @default.
• W2804486346 cites W1966292844 @default.
• W2804486346 cites W1970127494 @default.
• W2804486346 cites W1978909278 @default.
• W2804486346 cites W1981368803 @default.
• W2804486346 cites W1982414605 @default.
• W2804486346 cites W1983466975 @default.
• W2804486346 cites W1984128556 @default.
• W2804486346 cites W1986007527 @default.
• W2804486346 cites W1986020192 @default.
• W2804486346 cites W1988216861 @default.
• W2804486346 cites W1989205855 @default.
• W2804486346 cites W1992835596 @default.
• W2804486346 cites W1996771592 @default.
• W2804486346 cites W1997216543 @default.
• W2804486346 cites W1999887177 @default.
• W2804486346 cites W2009734832 @default.
• W2804486346 cites W2010258632 @default.
• W2804486346 cites W2013393598 @default.
• W2804486346 cites W2013581346 @default.
• W2804486346 cites W2014704178 @default.
• W2804486346 cites W2020463771 @default.
• W2804486346 cites W2022611080 @default.
• W2804486346 cites W2022714449 @default.
• W2804486346 cites W2023950511 @default.
• W2804486346 cites W2030921952 @default.
• W2804486346 cites W2033412312 @default.
• W2804486346 cites W2037338046 @default.
• W2804486346 cites W2040087566 @default.
• W2804486346 cites W2041511900 @default.
• W2804486346 cites W2047556450 @default.
• W2804486346 cites W2049349506 @default.
• W2804486346 cites W2051569518 @default.
• W2804486346 cites W2058669530 @default.
• W2804486346 cites W2060745946 @default.
• W2804486346 cites W2060805189 @default.
• W2804486346 cites W2071805256 @default.
• W2804486346 cites W2072165482 @default.
• W2804486346 cites W2077881562 @default.
• W2804486346 cites W2079105963 @default.
• W2804486346 cites W2079696602 @default.
• W2804486346 cites W2082029971 @default.
• W2804486346 cites W2083222334 @default.
• W2804486346 cites W2084949800 @default.
• W2804486346 cites W2086980373 @default.
• W2804486346 cites W2090616168 @default.
• W2804486346 cites W2091392139 @default.
• W2804486346 cites W2091775405 @default.
• W2804486346 cites W2120328266 @default.
• W2804486346 cites W2142857872 @default.
• W2804486346 cites W2145931541 @default.
• W2804486346 cites W2152103620 @default.
• W2804486346 cites W2162287352 @default.
• W2804486346 cites W2266078159 @default.
• W2804486346 cites W2315553885 @default.
• W2804486346 cites W2319295956 @default.
• W2804486346 cites W2342085745 @default.
• W2804486346 cites W2416646472 @default.
• W2804486346 cites W2506760706 @default.
• W2804486346 cites W2588520044 @default.
• W2804486346 cites W2744061662 @default.
• W2804486346 doi "https://doi.org/10.1021/acs.jpcc.8b03556" @default.
• W2804486346 hasPublicationYear "2018" @default.
• W2804486346 type Work @default.
• W2804486346 sameAs 2804486346 @default.
• W2804486346 citedByCount "16" @default.
• W2804486346 countsByYear W28044863462018 @default.
• W2804486346 countsByYear W28044863462019 @default.
• W2804486346 countsByYear W28044863462020 @default.
• W2804486346 countsByYear W28044863462021 @default.
• W2804486346 countsByYear W28044863462022 @default.
• W2804486346 countsByYear W28044863462023 @default.
• W2804486346 crossrefType "journal-article" @default.
• W2804486346 hasAuthorship W2804486346A5022371820 @default.
• W2804486346 hasAuthorship W2804486346A5027366818 @default.
• W2804486346 hasAuthorship W2804486346A5044714370 @default.
• W2804486346 hasAuthorship W2804486346A5052065929 @default.
• W2804486346 hasAuthorship W2804486346A5054988983 @default.
• W2804486346 hasAuthorship W2804486346A5059373986 @default.
• W2804486346 hasAuthorship W2804486346A5072220519 @default.
• W2804486346 hasAuthorship W2804486346A5072645578 @default.

• next