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- W2804524881 abstract "Methylammonium lead iodide (CH3NH3PbI3) is an extensively used perovskite material with a remarkable potential for solar energy conversion. Despite its high photovoltaic efficiency, the material suffers from fast degradation when aging in atmospheric conditions and/or under sunlight. Here we review the principal degradation mechanisms of CH3NH3PbI3, focusing on the thermodynamic, environmental and polymorphic parameters that impact the stability of the material. A critical analysis of the available data indicates that degradation under ambient conditions is a defect-generation process that is highly localized on surfaces and interfaces, while it is further enhanced above the tetragonal-cubic transition at ∼54 °C. Within this context, we discuss the conservative role of N2 and propose strategies for the emergence of industrially viable hybrid photovoltaics." @default.
- W2804524881 created "2018-06-01" @default.
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- W2804524881 date "2018-05-15" @default.
- W2804524881 modified "2023-10-18" @default.
- W2804524881 title "Stability and Degradation in Hybrid Perovskites: Is the Glass Half-Empty or Half-Full?" @default.
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- W2804524881 doi "https://doi.org/10.1021/acs.jpclett.8b00120" @default.
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