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• W2804579943 abstract "The reactions of hexaazamacrocycle 1 with 2,6-bis(bromomethyl)pyridine or 2,6-bis[(tosyloxy)methyl)]pyridine in the presence of appropriate carbonates result in the formation of derivatives of cryptand 6: enantiopure azacryptates of sodium and potassium. Crystal structures of these compounds indicate interaction of a metal ion with four pyridine nitrogen atoms and four tertiary amine atoms. The competition reactions monitored by NMR spectroscopy indicate preferential binding of Na+ over K+ as well as higher affinity of 6 for Na+ in comparison with the [2.2.1] cryptand." @default.
• W2804579943 created "2018-06-01" @default.
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• W2804579943 date "2018-05-18" @default.
• W2804579943 modified "2023-09-29" @default.
• W2804579943 title "Chiral Cryptates Derived from a Hexaazamacrocycle" @default.
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• W2804579943 doi "https://doi.org/10.1021/acs.joc.8b00670" @default.
• W2804579943 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/29774743" @default.
• W2804579943 hasPublicationYear "2018" @default.
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