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- W2804773676 abstract "We present a series of monometallic ([Cu(Mabiq)OTf] (1) and [Cu(Mabiq)] (2)) and bimetallic copper-Mabiq complexes ([Cu2(Mabiq)(PPh3)2(OTf)2] (3) and [Cu2(Mabiq)(PPh3)2]PF6 (4)). The latter compounds contain an additional CuI center that binds in a tetrahedral fashion to the external bipyrimidine nitrogens of the macrocyclic ligand. Compounds 3 and 4 represent the first examples of bimetallic transition metal Mabiq complexes, stable both in solution and in the solid state. The structural and electronic properties of compounds 1–4 were analyzed by means of X-ray crystallography, cyclic voltammetry, and spectroscopic methods. One-electron reduced 2 and 4 consist of a CuII ion coordinated by a Mabiq ligand radical, [CuII(Mabiq•)]. Thus, both bimetallic compounds are mixed-valent with respect to the copper oxidation states. Complexes 2 and 4 can be generated photochemically, upon irradiation of 1 or 3 with visible light in the presence of a sacrificial electron donor." @default.
- W2804773676 created "2018-06-01" @default.
- W2804773676 creator A5023609771 @default.
- W2804773676 creator A5024840132 @default.
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- W2804773676 date "2018-05-16" @default.
- W2804773676 modified "2023-09-27" @default.
- W2804773676 title "Structural Characterization and Photochemical Properties of Mono- and Bimetallic Cu-Mabiq Complexes" @default.
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- W2804773676 doi "https://doi.org/10.1021/acs.inorgchem.8b00471" @default.
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- W2804773676 hasPublicationYear "2018" @default.
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