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• W2804835369 startingPage "10488" @default.
• W2804835369 abstract "3-Nitro-4-(5-nitro-1,2,4-triazol-3-yl)furazan (2), N,N'-bis(trinitroethyl)-3,5'-diamino-4-(1,2,4-triazol-3-yl)furazan (3), N,N'-bis(trinitroethyl)-3,5'-dinitramino-4-(1,2,4-triazol-3-yl)furazan (4) and eighteen nitrogen-rich salts (5 a, 5 b, 5 d-5 i, 5 g-1, 6 a-6 i) were designed and synthesized. These 4-(1,2,4-triazole-5-yl)furazan derivatives were fully characterized by IR and NMR spectra, elemental analysis, and differential scanning calorimetry (DSC). The solid-state structures of 2, 5 d, 5 e, 5 h, 5 g-1, 6 g, and 6 i were confirmed via single crystal X-ray analysis. Detonation performance (detonation velocities and pressures) of these energetic compounds was evaluated and the impact and friction sensitivities were measured using standard BAM technology. Some of the compounds, for example, 2 (D: 9152 m s-1 , P=37.1 GPa) and 4 (D: 9355 m s-1 , P=40.1 GPa) exhibit excellent detonation performance, which are comparable to the highly explosive benchmarks such as RDX (D: 8795 m s-1 , P=34.9 GPa) and HMX (D: 9144 m s-1 , P=39.2 GPa)." @default.
• W2804835369 created "2018-06-01" @default.
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• W2804835369 date "2018-06-25" @default.
• W2804835369 modified "2023-10-05" @default.
• W2804835369 title "Synthesis and Characterization of 4-(1,2,4-Triazole-5-yl)furazan Derivatives as High-Performance Insensitive Energetic Materials" @default.
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• W2804835369 doi "https://doi.org/10.1002/chem.201801597" @default.
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