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- W280488165 abstract "This chapter presents the review of organic and physical chemistry of monocyclic 1, 2, 5-thiadiazoles up to the early part of 1967. Reference is made to the 2, 1, 3-benzothiadiazoles and related compounds only as they contribute to the chemistry of the basic ring system. The 1, 2, 5-thiadiazole nucleus is numbered as in 4. The hydrogenated forms are referred to as 1, 2, 5-thiadiazoline and 1, 2, 5-thiadiazolidine. The benzo derivatives are numbered and are named 2, 1, 3-benzothiadiazole, though much of the early literature makes use of the name piazthiole. The 1, 2, 5-thiadiazoles are very stable thermally. The unsubstituted ring is unchanged on heating at 220° and it has been reported that the potassium salt of 3-cyano-4-hydroxy-l, 2, 5-thiadiazoilse has table up to 360°. 1, 2, 5-thiadiazole generally resists electrophilic substitution. The compound is inert under various conditions of halogenation and nitration, and fails to enter the reactions with benzoyl chloride and aluminum chloride." @default.
- W280488165 created "2016-06-24" @default.
- W280488165 creator A5031579981 @default.
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- W280488165 date "1968-01-01" @default.
- W280488165 modified "2023-09-25" @default.
- W280488165 title "The 1,2,5-Thiadiazoles" @default.
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- W280488165 doi "https://doi.org/10.1016/s0065-2725(08)60372-4" @default.
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