Matches in SemOpenAlex for { <https://semopenalex.org/work/W2804983670> ?p ?o ?g. }
Showing items 1 to 92 of
92
with 100 items per page.
- W2804983670 endingPage "182" @default.
- W2804983670 startingPage "177" @default.
- W2804983670 abstract "Abstract The crystal structure, physical properties and photoelectrochemical characterization of a new single crystal hybrid semiconductor, based on α-Keggin-type polyoxometalate and 1H-1,2,4-triazole [trz] assembling [(Htrz)3][PW12O40].6H2O is studied for the first time. The single-crystal X-ray diffraction of the compound, synthesized by hydrothermal method, reveals an organic-inorganic hybrid framework constructed from Keggin anions [PW12O40]3+ with three monocationic triazoles, and six water molecules and crystallizing in R 3 ¯ space group. Further characterizations by FT-IR and Raman spectroscopy, thermal analysis and UV–Vis absorption spectra support the molecular formula. The optical study shows two transitions, directly (3.30 eV) and indirectly allowed (3.12 eV) attributed to Keggin anions. The semiconductor behavior is revealed by the electrical conductivity measurement, which follows an Arrhenius-type law with activation energy of 33 meV and electron mobility of 9.4 10−6 cm2 V−1 s−1. The photo-electrochemical study, performed in Na2SO4 medium, indicates n-type conduction with a flat band potential of -0.33 VSCE and electrons density of 2.14 1017 cm−3." @default.
- W2804983670 created "2018-06-01" @default.
- W2804983670 creator A5009359662 @default.
- W2804983670 creator A5035285250 @default.
- W2804983670 creator A5036526422 @default.
- W2804983670 creator A5053387229 @default.
- W2804983670 creator A5067703923 @default.
- W2804983670 date "2018-08-01" @default.
- W2804983670 modified "2023-10-16" @default.
- W2804983670 title "Structural, physical and photoelectrochemical characterization of a new semiconductor single crystal: [(Htrz)3][PW12O40].6H2O" @default.
- W2804983670 cites W1977282170 @default.
- W2804983670 cites W1978365970 @default.
- W2804983670 cites W1980576199 @default.
- W2804983670 cites W1997945719 @default.
- W2804983670 cites W2004749441 @default.
- W2804983670 cites W2023302782 @default.
- W2804983670 cites W2025721238 @default.
- W2804983670 cites W2055383154 @default.
- W2804983670 cites W2060318872 @default.
- W2804983670 cites W2116678111 @default.
- W2804983670 cites W2177717955 @default.
- W2804983670 cites W2197723393 @default.
- W2804983670 cites W2211124891 @default.
- W2804983670 cites W2216173369 @default.
- W2804983670 cites W2238098870 @default.
- W2804983670 cites W2345900665 @default.
- W2804983670 cites W2346405386 @default.
- W2804983670 cites W2361461606 @default.
- W2804983670 cites W2463478360 @default.
- W2804983670 cites W2466132823 @default.
- W2804983670 cites W2467388877 @default.
- W2804983670 cites W2502727433 @default.
- W2804983670 cites W2749691440 @default.
- W2804983670 cites W2769578101 @default.
- W2804983670 cites W2782055058 @default.
- W2804983670 cites W2789163955 @default.
- W2804983670 cites W2791301478 @default.
- W2804983670 cites W2793961501 @default.
- W2804983670 cites W2802169371 @default.
- W2804983670 doi "https://doi.org/10.1016/j.ica.2018.05.019" @default.
- W2804983670 hasPublicationYear "2018" @default.
- W2804983670 type Work @default.
- W2804983670 sameAs 2804983670 @default.
- W2804983670 citedByCount "5" @default.
- W2804983670 countsByYear W28049836702020 @default.
- W2804983670 countsByYear W28049836702021 @default.
- W2804983670 countsByYear W28049836702022 @default.
- W2804983670 countsByYear W28049836702023 @default.
- W2804983670 crossrefType "journal-article" @default.
- W2804983670 hasAuthorship W2804983670A5009359662 @default.
- W2804983670 hasAuthorship W2804983670A5035285250 @default.
- W2804983670 hasAuthorship W2804983670A5036526422 @default.
- W2804983670 hasAuthorship W2804983670A5053387229 @default.
- W2804983670 hasAuthorship W2804983670A5067703923 @default.
- W2804983670 hasConcept C108225325 @default.
- W2804983670 hasConcept C121332964 @default.
- W2804983670 hasConcept C171250308 @default.
- W2804983670 hasConcept C185592680 @default.
- W2804983670 hasConcept C192562407 @default.
- W2804983670 hasConcept C2780841128 @default.
- W2804983670 hasConcept C49040817 @default.
- W2804983670 hasConcept C73922627 @default.
- W2804983670 hasConcept C8010536 @default.
- W2804983670 hasConceptScore W2804983670C108225325 @default.
- W2804983670 hasConceptScore W2804983670C121332964 @default.
- W2804983670 hasConceptScore W2804983670C171250308 @default.
- W2804983670 hasConceptScore W2804983670C185592680 @default.
- W2804983670 hasConceptScore W2804983670C192562407 @default.
- W2804983670 hasConceptScore W2804983670C2780841128 @default.
- W2804983670 hasConceptScore W2804983670C49040817 @default.
- W2804983670 hasConceptScore W2804983670C73922627 @default.
- W2804983670 hasConceptScore W2804983670C8010536 @default.
- W2804983670 hasLocation W28049836701 @default.
- W2804983670 hasOpenAccess W2804983670 @default.
- W2804983670 hasPrimaryLocation W28049836701 @default.
- W2804983670 hasRelatedWork W1987114503 @default.
- W2804983670 hasRelatedWork W2054187252 @default.
- W2804983670 hasRelatedWork W2395151676 @default.
- W2804983670 hasRelatedWork W2399081566 @default.
- W2804983670 hasRelatedWork W2493673863 @default.
- W2804983670 hasRelatedWork W2508480375 @default.
- W2804983670 hasRelatedWork W2952541249 @default.
- W2804983670 hasRelatedWork W3037456415 @default.
- W2804983670 hasRelatedWork W311682869 @default.
- W2804983670 hasRelatedWork W574427456 @default.
- W2804983670 hasVolume "480" @default.
- W2804983670 isParatext "false" @default.
- W2804983670 isRetracted "false" @default.
- W2804983670 magId "2804983670" @default.
- W2804983670 workType "article" @default.