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- W2805009752 abstract "Abstract Precise control of host–guest interaction as seen in biological processes is difficult to achieve with artificial systems. Herein we have exploited the thermodynamic benefits of a system in equilibrium to achieve controlled stepwise release and capture of cyclodextrin (guest) using a coordination polymer (Mg-CP) as the host and temperature as the stimulus. Since temperature is not a precision stimulus for artificial host–guest interaction, the present system is a distinct prototype that manifests temperature-controlled natural host–guest interaction. The described coordination polymeric host system, when incorporated into a hydrogel matrix, provides a microenvironment that facilitates the stepwise release of α -CD in response to temperature variation within a quasi-solid state. The work demonstrated here may pave the way towards thermally controlled delivery and monitoring of otherwise spectroscopically silent molecules such as cyclodextrins." @default.
- W2805009752 created "2018-06-01" @default.
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- W2805009752 date "2018-05-18" @default.
- W2805009752 modified "2023-10-12" @default.
- W2805009752 title "Stepwise control of host–guest interaction using a coordination polymer gel" @default.
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- W2805009752 doi "https://doi.org/10.1038/s41467-018-04303-8" @default.
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