Matches in SemOpenAlex for { <https://semopenalex.org/work/W2805044374> ?p ?o ?g. }
- W2805044374 endingPage "8305" @default.
- W2805044374 startingPage "8301" @default.
- W2805044374 abstract "Arene-stabilized silylium ions react with carbon monoxide rather than carbon monoxide adducts of silylium ions reacting with arenes. This mechanism is supported by quantum-chemical calculations. Even sterically hindered mesitylene and electronically deactivated chlorobenzene engage in this electrophilic aromatic substitution. The silylium ion mediated formylation corresponds to Gattermann-Koch reactions promoted by strong Brønsted acids. The resulting silylcarboxonium ion of the arenecarbaldehyde was crystallographically characterized, for the first time revealing the molecular structure of this synthetically important intermediate." @default.
- W2805044374 created "2018-06-13" @default.
- W2805044374 creator A5002792140 @default.
- W2805044374 creator A5007685801 @default.
- W2805044374 creator A5013102775 @default.
- W2805044374 creator A5072474749 @default.
- W2805044374 creator A5075734962 @default.
- W2805044374 creator A5077327204 @default.
- W2805044374 date "2018-05-30" @default.
- W2805044374 modified "2023-10-14" @default.
- W2805044374 title "Electrophilic Formylation of Arenes by Silylium Ion Mediated Activation of Carbon Monoxide" @default.
- W2805044374 cites W122765331 @default.
- W2805044374 cites W1565508162 @default.
- W2805044374 cites W1616998407 @default.
- W2805044374 cites W1880541354 @default.
- W2805044374 cites W1957584270 @default.
- W2805044374 cites W1983998009 @default.
- W2805044374 cites W1986672150 @default.
- W2805044374 cites W1988091937 @default.
- W2805044374 cites W1988121434 @default.
- W2805044374 cites W1988906747 @default.
- W2805044374 cites W1996349662 @default.
- W2805044374 cites W1999233801 @default.
- W2805044374 cites W1999533010 @default.
- W2805044374 cites W2002867842 @default.
- W2805044374 cites W2004171170 @default.
- W2805044374 cites W2005728854 @default.
- W2805044374 cites W2006140177 @default.
- W2805044374 cites W2009249798 @default.
- W2805044374 cites W2015350467 @default.
- W2805044374 cites W2016800344 @default.
- W2805044374 cites W2022647292 @default.
- W2805044374 cites W2030894031 @default.
- W2805044374 cites W2032719166 @default.
- W2805044374 cites W2037570317 @default.
- W2805044374 cites W2037703910 @default.
- W2805044374 cites W2040965923 @default.
- W2805044374 cites W2044418114 @default.
- W2805044374 cites W2055563809 @default.
- W2805044374 cites W2057390396 @default.
- W2805044374 cites W2057852366 @default.
- W2805044374 cites W2064811421 @default.
- W2805044374 cites W2070954147 @default.
- W2805044374 cites W2071235105 @default.
- W2805044374 cites W2073328513 @default.
- W2805044374 cites W2082037815 @default.
- W2805044374 cites W2082443721 @default.
- W2805044374 cites W2088121384 @default.
- W2805044374 cites W2092157292 @default.
- W2805044374 cites W2093888100 @default.
- W2805044374 cites W2096747776 @default.
- W2805044374 cites W2097615292 @default.
- W2805044374 cites W2099618458 @default.
- W2805044374 cites W2105776331 @default.
- W2805044374 cites W2112718758 @default.
- W2805044374 cites W2116346507 @default.
- W2805044374 cites W2119547517 @default.
- W2805044374 cites W2121112822 @default.
- W2805044374 cites W2123115112 @default.
- W2805044374 cites W2131565822 @default.
- W2805044374 cites W2132795750 @default.
- W2805044374 cites W2143763673 @default.
- W2805044374 cites W2148238597 @default.
- W2805044374 cites W2235502827 @default.
- W2805044374 cites W2312645791 @default.
- W2805044374 cites W2312934384 @default.
- W2805044374 cites W2329744712 @default.
- W2805044374 cites W2746392862 @default.
- W2805044374 cites W2767436846 @default.
- W2805044374 cites W2770977582 @default.
- W2805044374 cites W2949525659 @default.
- W2805044374 cites W2951250856 @default.
- W2805044374 cites W2951324661 @default.
- W2805044374 cites W2952207072 @default.
- W2805044374 cites W31818547 @default.
- W2805044374 cites W4211034308 @default.
- W2805044374 cites W4230482997 @default.
- W2805044374 cites W4241277916 @default.
- W2805044374 cites W4245716416 @default.
- W2805044374 cites W4248183902 @default.
- W2805044374 cites W4248889273 @default.
- W2805044374 cites W4256115356 @default.
- W2805044374 doi "https://doi.org/10.1002/anie.201803181" @default.
- W2805044374 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/29741219" @default.
- W2805044374 hasPublicationYear "2018" @default.
- W2805044374 type Work @default.
- W2805044374 sameAs 2805044374 @default.
- W2805044374 citedByCount "31" @default.
- W2805044374 countsByYear W28050443742018 @default.
- W2805044374 countsByYear W28050443742019 @default.
- W2805044374 countsByYear W28050443742020 @default.
- W2805044374 countsByYear W28050443742021 @default.
- W2805044374 countsByYear W28050443742022 @default.
- W2805044374 countsByYear W28050443742023 @default.
- W2805044374 crossrefType "journal-article" @default.
- W2805044374 hasAuthorship W2805044374A5002792140 @default.
- W2805044374 hasAuthorship W2805044374A5007685801 @default.
- W2805044374 hasAuthorship W2805044374A5013102775 @default.