Matches in SemOpenAlex for { <https://semopenalex.org/work/W2805248384> ?p ?o ?g. }
- W2805248384 endingPage "341" @default.
- W2805248384 startingPage "333" @default.
- W2805248384 abstract "In this study, the perichromic behavior of bromophenol blue (BPB) in various binary solvent mixtures was investigated. The binary mixtures considered were comprised of water and methanol (MeOH), ethanol (EtOH), n-propanol (n-PrOH), isopropanol (iso-PrOH) or t-butanol (t-BuOH). The investigation of a preferential solvation model that considers the addition of small quantities of alcohol to water in the presence of bromophenol blue (BPB) is described in this paper. The data obtained were employed to study the preferential solvation (PS) of the probe. It was observed that with increases in the molar fraction of water the spontaneity of the system decreases. This can be explained by the high solubility of BPB in ethanol, with ∆G > 0 at higher wavelengths (region rich in water with violet solution) and ∆G < 0 at lower wavelengths (region rich in alcohol with yellow solution). The pK of the binary mixture changed in all solvents and for all ratios, and the higher the water ratio is the lower the pKIn will be. In binary mixture, an increase in the hydrogen bond acceptor (HBA) nature of the solvents tested resulted in a bathochromic effect on the absorption band of BPB (Δλ = 12 nm). All of the data obtained showed a good nonlinear fit with the mathematical model (SD ≤ 6.6 × 10−3), suggesting that BPB has other potential applications besides its use as a pH indicator." @default.
- W2805248384 created "2018-06-13" @default.
- W2805248384 creator A5000092140 @default.
- W2805248384 creator A5006355745 @default.
- W2805248384 creator A5021736998 @default.
- W2805248384 creator A5055556628 @default.
- W2805248384 creator A5065624667 @default.
- W2805248384 creator A5089515261 @default.
- W2805248384 date "2018-10-01" @default.
- W2805248384 modified "2023-10-14" @default.
- W2805248384 title "Preferential solvation bromophenol blue in water-alcohol binary mixture" @default.
- W2805248384 cites W1966858197 @default.
- W2805248384 cites W1980825543 @default.
- W2805248384 cites W1986365428 @default.
- W2805248384 cites W2008104421 @default.
- W2805248384 cites W2013270593 @default.
- W2805248384 cites W2017340529 @default.
- W2805248384 cites W2022934937 @default.
- W2805248384 cites W2028366105 @default.
- W2805248384 cites W2040395618 @default.
- W2805248384 cites W2049040357 @default.
- W2805248384 cites W2057003691 @default.
- W2805248384 cites W2069287093 @default.
- W2805248384 cites W2078541352 @default.
- W2805248384 cites W2084767356 @default.
- W2805248384 cites W2085293715 @default.
- W2805248384 cites W2090391132 @default.
- W2805248384 cites W2091850769 @default.
- W2805248384 cites W2105796412 @default.
- W2805248384 cites W2117492861 @default.
- W2805248384 cites W2123341250 @default.
- W2805248384 cites W2124112297 @default.
- W2805248384 cites W2127806790 @default.
- W2805248384 cites W2161709368 @default.
- W2805248384 cites W2171576223 @default.
- W2805248384 cites W2301448284 @default.
- W2805248384 cites W2334824702 @default.
- W2805248384 cites W2552756632 @default.
- W2805248384 cites W2560785030 @default.
- W2805248384 cites W2792050031 @default.
- W2805248384 cites W2802248128 @default.
- W2805248384 doi "https://doi.org/10.1016/j.saa.2018.05.087" @default.
- W2805248384 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/29885632" @default.
- W2805248384 hasPublicationYear "2018" @default.
- W2805248384 type Work @default.
- W2805248384 sameAs 2805248384 @default.
- W2805248384 citedByCount "5" @default.
- W2805248384 countsByYear W28052483842019 @default.
- W2805248384 countsByYear W28052483842021 @default.
- W2805248384 countsByYear W28052483842023 @default.
- W2805248384 crossrefType "journal-article" @default.
- W2805248384 hasAuthorship W2805248384A5000092140 @default.
- W2805248384 hasAuthorship W2805248384A5006355745 @default.
- W2805248384 hasAuthorship W2805248384A5021736998 @default.
- W2805248384 hasAuthorship W2805248384A5055556628 @default.
- W2805248384 hasAuthorship W2805248384A5065624667 @default.
- W2805248384 hasAuthorship W2805248384A5089515261 @default.
- W2805248384 hasConcept C112887158 @default.
- W2805248384 hasConcept C113196181 @default.
- W2805248384 hasConcept C121332964 @default.
- W2805248384 hasConcept C147789679 @default.
- W2805248384 hasConcept C148093993 @default.
- W2805248384 hasConcept C155574463 @default.
- W2805248384 hasConcept C178790620 @default.
- W2805248384 hasConcept C185592680 @default.
- W2805248384 hasConcept C2779607525 @default.
- W2805248384 hasConcept C2780418270 @default.
- W2805248384 hasConcept C2780471494 @default.
- W2805248384 hasConcept C2781066024 @default.
- W2805248384 hasConcept C32909587 @default.
- W2805248384 hasConcept C36591836 @default.
- W2805248384 hasConcept C43617362 @default.
- W2805248384 hasConcept C46051903 @default.
- W2805248384 hasConcept C62520636 @default.
- W2805248384 hasConcept C67218372 @default.
- W2805248384 hasConcept C91881484 @default.
- W2805248384 hasConceptScore W2805248384C112887158 @default.
- W2805248384 hasConceptScore W2805248384C113196181 @default.
- W2805248384 hasConceptScore W2805248384C121332964 @default.
- W2805248384 hasConceptScore W2805248384C147789679 @default.
- W2805248384 hasConceptScore W2805248384C148093993 @default.
- W2805248384 hasConceptScore W2805248384C155574463 @default.
- W2805248384 hasConceptScore W2805248384C178790620 @default.
- W2805248384 hasConceptScore W2805248384C185592680 @default.
- W2805248384 hasConceptScore W2805248384C2779607525 @default.
- W2805248384 hasConceptScore W2805248384C2780418270 @default.
- W2805248384 hasConceptScore W2805248384C2780471494 @default.
- W2805248384 hasConceptScore W2805248384C2781066024 @default.
- W2805248384 hasConceptScore W2805248384C32909587 @default.
- W2805248384 hasConceptScore W2805248384C36591836 @default.
- W2805248384 hasConceptScore W2805248384C43617362 @default.
- W2805248384 hasConceptScore W2805248384C46051903 @default.
- W2805248384 hasConceptScore W2805248384C62520636 @default.
- W2805248384 hasConceptScore W2805248384C67218372 @default.
- W2805248384 hasConceptScore W2805248384C91881484 @default.
- W2805248384 hasFunder F4320322025 @default.
- W2805248384 hasFunder F4320322772 @default.
- W2805248384 hasLocation W28052483841 @default.