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• W2805346318 abstract "Abstract It is presented for the first time nontoxic CuGaS 2 /ZnS quantum dots (QDs) with free‐self‐reabsorption losses and large Stokes shift (>190 nm) synthesized on an industrially gram‐scale as an alternative for Cd‐based energy‐downshift (EDS)‐QD layers. The QDs exhibit a typical EDS that absorbs only UV light (<407 nm) and emits the whole range of visible light (400–800 nm) with a high photoluminescence‐quantum yield of ≈76%. The straightforward application of these EDS‐QDs on the front surface of a monocrystalline p‐type silicon solar cell significantly enhances the short‐circuit current density by ≈1.64 mA cm −2 (+4.20%); thereby, improving the power‐conversion‐efficiency by ≈4.11%. The significant improvement in the external quantum efficiency increases by ≈35.7% and that in the surface reflectance decreases by ≈14.1% in the UV region (300–450 nm) clearly manifest the photovoltaic enhancement. Such promising results together with the simple (one‐pot core/shell synthesis), cost‐effective (reduction in a bill of material–system by ≈2.62%), and scalable (2000 mL three‐neck flask, 11 g of QDs) preparation process might encourage the manufacturers of solar cells and other optoelectronic applications to apply these EDS‐QDs to different broader eco‐friendly applications." @default.
• W2805346318 created "2018-06-13" @default.
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• W2805346318 date "2018-06-07" @default.
• W2805346318 modified "2023-10-06" @default.
• W2805346318 title "One-Pot Gram-Scale, Eco-Friendly, and Cost-Effective Synthesis of CuGaS₂ /ZnS Nanocrystals as Efficient UV-Harvesting Down-Converter for Photovoltaics" @default.
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• W2805346318 doi "https://doi.org/10.1002/aenm.201703418" @default.
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