FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2805685369> ?p ?o ?g. }

• W2805685369 abstract "Abstract In natural ionic solids, cationic and anionic species are alternately arranged to minimize electrostatic energy. Aggregation of identical ionic species is commonly prohibited due to the repulsive, long-range nature of Coulombic interactions. Recently, we synthesized unique ionic solids, [Au I 4 Co III 2 (dppe) 2 ( d -pen) 4 ]X 2 · n H 2 O (dppe = 1,2-bis(diphenylphosphino)ethane, d -pen = d -penicillaminate), in which complex cations are self-assembled into a cationic supramolecular octahedron, while monovalent or divalent inorganic anions are aggregated into an anomalous anionic cluster accommodating several water molecules. This quite unusual aggregation manner originates from various molecular-level non-Coulombic interactions such as hydrogen bonds and CH-π interactions; thus, this class of ionic solids is referred to as non-Coulombic ionic solids, abbreviated as NCISs. Herein, we report that the NCISs with a peculiar charge-separated (CS) structure in a cubic lattice show a negative, isotropic electrostriction phenomenon that has never been found in any ionic solids, as well as an anomalously large relaxer-like dielectric jump phenomenon reaching to an application level of ε ′/ ε 0 ~ 10 5 . The appearance of these phenomena was explained by the cooperative dynamics of inorganic anions and dipolar water molecules in the pliable anionic clusters that are surrounded by a rather robust cationic metallosupramolecular framework with a meso-scopic scale." @default.
• W2805685369 created "2018-06-13" @default.
• W2805685369 creator A5000133393 @default.
• W2805685369 creator A5024217952 @default.
• W2805685369 creator A5031172003 @default.
• W2805685369 creator A5055046362 @default.
• W2805685369 creator A5067382126 @default.
• W2805685369 creator A5082539520 @default.
• W2805685369 creator A5090678127 @default.
• W2805685369 date "2018-02-08" @default.
• W2805685369 modified "2023-10-17" @default.
• W2805685369 title "Dielectric Jump and Negative Electrostriction in Metallosupramolecular Ionic Crystals" @default.
• W2805685369 cites W1969786501 @default.
• W2805685369 cites W2017709097 @default.
• W2805685369 cites W2018904716 @default.
• W2805685369 cites W2044293773 @default.
• W2805685369 cites W2049254359 @default.
• W2805685369 cites W2079471355 @default.
• W2805685369 cites W2081211064 @default.
• W2805685369 cites W2086936998 @default.
• W2805685369 cites W2087763550 @default.
• W2805685369 cites W2137373239 @default.
• W2805685369 cites W2313816707 @default.
• W2805685369 cites W2327962536 @default.
• W2805685369 cites W2407637344 @default.
• W2805685369 cites W2953007067 @default.
• W2805685369 cites W4206351573 @default.
• W2805685369 doi "https://doi.org/10.1038/s41598-018-20750-1" @default.
• W2805685369 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/5805720" @default.
• W2805685369 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/29422649" @default.
• W2805685369 hasPublicationYear "2018" @default.
• W2805685369 type Work @default.
• W2805685369 sameAs 2805685369 @default.
• W2805685369 citedByCount "10" @default.
• W2805685369 countsByYear W28056853692019 @default.
• W2805685369 countsByYear W28056853692020 @default.
• W2805685369 countsByYear W28056853692021 @default.
• W2805685369 countsByYear W28056853692023 @default.
• W2805685369 crossrefType "journal-article" @default.
• W2805685369 hasAuthorship W2805685369A5000133393 @default.
• W2805685369 hasAuthorship W2805685369A5024217952 @default.
• W2805685369 hasAuthorship W2805685369A5031172003 @default.
• W2805685369 hasAuthorship W2805685369A5055046362 @default.
• W2805685369 hasAuthorship W2805685369A5067382126 @default.
• W2805685369 hasAuthorship W2805685369A5082539520 @default.
• W2805685369 hasAuthorship W2805685369A5090678127 @default.
• W2805685369 hasBestOaLocation W28056853691 @default.
• W2805685369 hasConcept C100082104 @default.
• W2805685369 hasConcept C112887158 @default.
• W2805685369 hasConcept C115624301 @default.
• W2805685369 hasConcept C117911374 @default.
• W2805685369 hasConcept C145148216 @default.
• W2805685369 hasConcept C159467904 @default.
• W2805685369 hasConcept C159985019 @default.
• W2805685369 hasConcept C178790620 @default.
• W2805685369 hasConcept C183882617 @default.
• W2805685369 hasConcept C185592680 @default.
• W2805685369 hasConcept C192562407 @default.
• W2805685369 hasConcept C2182769 @default.
• W2805685369 hasConcept C32909587 @default.
• W2805685369 hasConcept C74884574 @default.
• W2805685369 hasConcept C8010536 @default.
• W2805685369 hasConcept C93275456 @default.
• W2805685369 hasConceptScore W2805685369C100082104 @default.
• W2805685369 hasConceptScore W2805685369C112887158 @default.
• W2805685369 hasConceptScore W2805685369C115624301 @default.
• W2805685369 hasConceptScore W2805685369C117911374 @default.
• W2805685369 hasConceptScore W2805685369C145148216 @default.
• W2805685369 hasConceptScore W2805685369C159467904 @default.
• W2805685369 hasConceptScore W2805685369C159985019 @default.
• W2805685369 hasConceptScore W2805685369C178790620 @default.
• W2805685369 hasConceptScore W2805685369C183882617 @default.
• W2805685369 hasConceptScore W2805685369C185592680 @default.
• W2805685369 hasConceptScore W2805685369C192562407 @default.
• W2805685369 hasConceptScore W2805685369C2182769 @default.
• W2805685369 hasConceptScore W2805685369C32909587 @default.
• W2805685369 hasConceptScore W2805685369C74884574 @default.
• W2805685369 hasConceptScore W2805685369C8010536 @default.
• W2805685369 hasConceptScore W2805685369C93275456 @default.
• W2805685369 hasIssue "1" @default.
• W2805685369 hasLocation W28056853691 @default.
• W2805685369 hasLocation W28056853692 @default.
• W2805685369 hasLocation W28056853693 @default.
• W2805685369 hasLocation W28056853694 @default.
• W2805685369 hasOpenAccess W2805685369 @default.
• W2805685369 hasPrimaryLocation W28056853691 @default.
• W2805685369 hasRelatedWork W1975944777 @default.
• W2805685369 hasRelatedWork W2008570602 @default.
• W2805685369 hasRelatedWork W2013152197 @default.
• W2805685369 hasRelatedWork W2033278446 @default.
• W2805685369 hasRelatedWork W2034446412 @default.
• W2805685369 hasRelatedWork W2081492955 @default.
• W2805685369 hasRelatedWork W2313208399 @default.
• W2805685369 hasRelatedWork W2387312718 @default.
• W2805685369 hasRelatedWork W90668318 @default.
• W2805685369 hasRelatedWork W2187419274 @default.
• W2805685369 hasVolume "8" @default.
• W2805685369 isParatext "false" @default.
• W2805685369 isRetracted "false" @default.
• W2805685369 magId "2805685369" @default.

• next