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- W2806001395 abstract "A novel carbon-increasing catalytic route via one-pot cascade acylation–alkylation of biomass-derived 2-methylfuran and acetic anhydride over Sn4+-exchanged K-10 montmorillonite (Sn4+-K-10) was demonstrated to be highly efficient for the production of C17 oxygenate 1,1,1-tris(5-methyl-2-furyl)ethane with a high yield of 87% and 90% selectivity at 60 °C in 8 h under solvent-free conditions. Characterization techniques manifested Sn4+-K-10 to have layered and mesoporous (5.7 nm) texture structure, Lewis–Brønsted acid paired sites and uniformly dispersed Sn species, which greatly contributed to the predominant reactivity and recyclability of Sn4+-K-10. Systematic studies based on GC–MS and NMR were also conducted to elucidate the catalytic mechanism." @default.
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- W2806001395 date "2018-10-01" @default.
- W2806001395 modified "2023-09-24" @default.
- W2806001395 title "Low-temperature and solvent-free production of biomass-derived diesel-range C17 precursor via one-pot cascade acylation–alkylation over Sn4+-montmorillonite" @default.
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- W2806001395 doi "https://doi.org/10.1016/j.jiec.2018.05.047" @default.
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