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- W2806079232 abstract "Abstract Porous organic polymers (POPs) have attracted significant attention towards molecular adsorption in recent years due to their high porosity, diverse functionality and excellent chemical stability. In this work, we present a systematic case study on the formation of thiazolo[5,4‐ d ]thiazole (TzTz) linkages through model compounds and its integration to synthesize a set of three novel, thermo‐chemically stable TzTz‐linked POPs, namely TzTz‐POP‐3 , TzTz‐POP‐4 , and TzTz‐POP‐5 with triphenylbenzene, tetraphenylpyrene and tetra(hydroxyphenyl)methane cores, respectively. Interestingly, the integrated TzTz moiety of the represented TzTz‐POP‐3 renders chemoselective removal of organic dye fluorescein (FL) from a mixture with parafuchsine (FU) in aqueous solution. The TzTz‐POP‐3 offered excellent chemoselectivity of ≈1:7 (FL:FU), compared to alike porous materials demonstrated for similar applications due to the presence of multiple active anchoring sites coupled with permanent porosity and appropriate pore window." @default.
- W2806079232 created "2018-06-13" @default.
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- W2806079232 date "2018-06-28" @default.
- W2806079232 modified "2023-10-17" @default.
- W2806079232 title "Exploration of Thiazolo[5,4‐<i>d</i>]thiazole Linkages in Conjugated Porous Organic Polymers for Chemoselective Molecular Sieving" @default.
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- W2806079232 doi "https://doi.org/10.1002/chem.201802631" @default.
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