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- W2806113337 abstract "By systematic change of the solvothermal synthesis, three new coordination polymers, [Cd(L)∙(H2O)]∙2H2O (1), [Cd(L)∙(H2O)]∙H2O (2), and [Cd(L)] (3), have been synthesized based on a tritopic ligand 4-(pyridin-3-yl)isophthalic acid (H2L). Compounds 1 and 2 show very similar two-dimensional (2D) bilayers further linked by interlayer hydrogen bonds into three-dimensional (3D) supramolecular structures, while 3 displays a 3D structure constructed form one-dimensional (1D) Cd-carboxyl chains. Notably, 1 and 2 have a pair of unusual isomers with the opposite orientation of coordinated H2O on the metal centers, leading to different hydrogen bonding interactions. Thermal stabilities and solid-state photoluminescences for 1–3 were also investigated." @default.
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- W2806113337 date "2018-06-18" @default.
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- W2806113337 title "Three Cd(II) coordination polymers based on a pyridyldicarboxylate: effect of coordinated water" @default.
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- W2806113337 doi "https://doi.org/10.1080/00958972.2018.1485899" @default.
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