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- W2806133519 abstract "Abstract Development of secondary zinc–air batteries goes through a proper specification of the electrolyte formulation adapted to extend the cycle life of the battery. However, defining an optimal formulation is not a trivial work due to the specific requirements for each electrode. At half‐cell level, it has been determined that ZnO‐saturated 4 mol L −1 KOH with 2 mol L −1 KF and 2 mol L −1 K 2 CO 3 (4s‐2) is the most suitable formulation to increase the cycle life of secondary zinc electrode, whereas additive‐free 8 mol L −1 KOH (8‐0) formulation is more beneficial for the bifunctional air electrode ( BAE ). Through this systematic cycle life assessment, it has been found that the most suitable electrolyte formulation for the full cell system is a compendium for both electrodes requirements. It has determined an optimal electrolyte formulation for the full system consisting of ZnO‐saturated 7 mol L −1 KOH with 1.4 mol L −1 KF and 1.4 mol L −1 K 2 CO 3 (7s‐1.4). This electrolyte composition increases at least 2.5 times the reversibility of the secondary zinc–air battery in comparison with that employing the traditional formulation for primary zinc–air batteries (additive‐free 8 mol L −1 KOH ). In addition, the development of a proper cell design or separator is also necessary to further enhance the secondary zinc–air cycle life." @default.
- W2806133519 created "2018-06-13" @default.
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- W2806133519 date "2018-05-29" @default.
- W2806133519 modified "2023-10-14" @default.
- W2806133519 title "Systematic cycle life assessment of a secondary zinc-air battery as a function of the alkaline electrolyte composition" @default.
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- W2806133519 doi "https://doi.org/10.1002/ese3.191" @default.
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