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- W2806196411 abstract "Abstract A bulky carboxylic acid bearing three cyclohexylmethyl substituents at the α‐position, namely, tri(cyclohexylmethyl)acetic acid, is demonstrated to act as an efficient ligand source in Pd‐catalyzed intramolecular C(sp 2 )−H and C(sp 3 )−H arylation reactions. The reactions proceed smoothly under mild reaction conditions, even at room temperature due to the steric bulk of the carboxylate ligands, which accelerates the rate‐determining C−H bond activation step in the catalytic cycle." @default.
- W2806196411 created "2018-06-13" @default.
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- W2806196411 date "2018-06-19" @default.
- W2806196411 modified "2023-10-16" @default.
- W2806196411 title "Steric Effect of Carboxylate Ligands on Pd-Catalyzed Intramolecular C(sp<sup>2</sup> )-H and C(sp<sup>3</sup> )-H Arylation Reactions" @default.
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- W2806196411 doi "https://doi.org/10.1002/anie.201804566" @default.
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