Matches in SemOpenAlex for { <https://semopenalex.org/work/W2806366957> ?p ?o ?g. }
Showing items 1 to 98 of
98
with 100 items per page.
- W2806366957 endingPage "1899" @default.
- W2806366957 startingPage "1892" @default.
- W2806366957 abstract "The chiral-at-metal complexes (RFe,RC)/(SFe,RC)-[CpFe(Prophos)NCR]X (X = I, PF6; R = Et, Ph, p-substituted Ph) were prepared, and the diastereomers were separated by fractional crystallization. Eight diastereomerically pure complexes (SFe,RC)-[CpFe(Prophos)NCR]X could be characterized by X-ray crystallography. The kinetics of epimerization with respect to the labile Fe-configuration in CDCl3 at ambient temperatures was measured for the EtCN, PhCN, and (p-C6H4NMe2) complexes. The half-lives of 162 and 760 min of the first-order reactions of (SFe,RC)-[CpFe(Prophos)NCPh]PF6 and (SFe,RC)-[CpFe(Prophos)NC(p-C6H4NMe2)]PF6 at 293 K demonstrate the importance of the inductive effect in the rate-determining cleavage of the Fe–NCR bond. The diastereomer ratios of 5:95 to 10:90 at equilibrium under thermodynamic control were strongly in favor of the (SFe,RC)-[CpFe(Prophos)NCR]X diastereomers. In ligand exchange reaction reactions, (RFe,RC)/(SFe,RC) diastereomer ratios of up to 35:65 were observed under kinetic control." @default.
- W2806366957 created "2018-06-13" @default.
- W2806366957 creator A5018197233 @default.
- W2806366957 creator A5019098060 @default.
- W2806366957 creator A5035864684 @default.
- W2806366957 creator A5039722512 @default.
- W2806366957 creator A5066479793 @default.
- W2806366957 date "2018-06-01" @default.
- W2806366957 modified "2023-09-23" @default.
- W2806366957 title "Kinetic and Thermodynamic Control of Nitrile Dissociation in the Complexes (<i>R</i><sub>Fe</sub>,<i>R</i><sub>C</sub>)/(<i>S</i><sub>Fe</sub>,<i>R</i><sub>C</sub>)-[CpFe(Prophos)NCR]X (X = I, PF<sub>6</sub>) by the Inductive Effect" @default.
- W2806366957 cites W1591099328 @default.
- W2806366957 cites W1967308727 @default.
- W2806366957 cites W1969360633 @default.
- W2806366957 cites W1969635440 @default.
- W2806366957 cites W1972687180 @default.
- W2806366957 cites W1975217371 @default.
- W2806366957 cites W2024039555 @default.
- W2806366957 cites W2030264829 @default.
- W2806366957 cites W2111600446 @default.
- W2806366957 cites W2315460925 @default.
- W2806366957 cites W2317052840 @default.
- W2806366957 cites W2319536114 @default.
- W2806366957 cites W2325164964 @default.
- W2806366957 cites W2335738873 @default.
- W2806366957 doi "https://doi.org/10.1021/acs.organomet.8b00146" @default.
- W2806366957 hasPublicationYear "2018" @default.
- W2806366957 type Work @default.
- W2806366957 sameAs 2806366957 @default.
- W2806366957 citedByCount "2" @default.
- W2806366957 countsByYear W28063669572020 @default.
- W2806366957 countsByYear W28063669572021 @default.
- W2806366957 crossrefType "journal-article" @default.
- W2806366957 hasAuthorship W2806366957A5018197233 @default.
- W2806366957 hasAuthorship W2806366957A5019098060 @default.
- W2806366957 hasAuthorship W2806366957A5035864684 @default.
- W2806366957 hasAuthorship W2806366957A5039722512 @default.
- W2806366957 hasAuthorship W2806366957A5066479793 @default.
- W2806366957 hasConcept C102931765 @default.
- W2806366957 hasConcept C116569031 @default.
- W2806366957 hasConcept C121332964 @default.
- W2806366957 hasConcept C135889238 @default.
- W2806366957 hasConcept C138716334 @default.
- W2806366957 hasConcept C147789679 @default.
- W2806366957 hasConcept C148898269 @default.
- W2806366957 hasConcept C155647269 @default.
- W2806366957 hasConcept C161790260 @default.
- W2806366957 hasConcept C170493617 @default.
- W2806366957 hasConcept C178790620 @default.
- W2806366957 hasConcept C185592680 @default.
- W2806366957 hasConcept C203036418 @default.
- W2806366957 hasConcept C203130289 @default.
- W2806366957 hasConcept C2779240715 @default.
- W2806366957 hasConcept C2991957519 @default.
- W2806366957 hasConcept C55493867 @default.
- W2806366957 hasConcept C62520636 @default.
- W2806366957 hasConcept C71240020 @default.
- W2806366957 hasConcept C8010536 @default.
- W2806366957 hasConceptScore W2806366957C102931765 @default.
- W2806366957 hasConceptScore W2806366957C116569031 @default.
- W2806366957 hasConceptScore W2806366957C121332964 @default.
- W2806366957 hasConceptScore W2806366957C135889238 @default.
- W2806366957 hasConceptScore W2806366957C138716334 @default.
- W2806366957 hasConceptScore W2806366957C147789679 @default.
- W2806366957 hasConceptScore W2806366957C148898269 @default.
- W2806366957 hasConceptScore W2806366957C155647269 @default.
- W2806366957 hasConceptScore W2806366957C161790260 @default.
- W2806366957 hasConceptScore W2806366957C170493617 @default.
- W2806366957 hasConceptScore W2806366957C178790620 @default.
- W2806366957 hasConceptScore W2806366957C185592680 @default.
- W2806366957 hasConceptScore W2806366957C203036418 @default.
- W2806366957 hasConceptScore W2806366957C203130289 @default.
- W2806366957 hasConceptScore W2806366957C2779240715 @default.
- W2806366957 hasConceptScore W2806366957C2991957519 @default.
- W2806366957 hasConceptScore W2806366957C55493867 @default.
- W2806366957 hasConceptScore W2806366957C62520636 @default.
- W2806366957 hasConceptScore W2806366957C71240020 @default.
- W2806366957 hasConceptScore W2806366957C8010536 @default.
- W2806366957 hasIssue "12" @default.
- W2806366957 hasLocation W28063669571 @default.
- W2806366957 hasOpenAccess W2806366957 @default.
- W2806366957 hasPrimaryLocation W28063669571 @default.
- W2806366957 hasRelatedWork W1899308044 @default.
- W2806366957 hasRelatedWork W2014150068 @default.
- W2806366957 hasRelatedWork W2073288112 @default.
- W2806366957 hasRelatedWork W2151228214 @default.
- W2806366957 hasRelatedWork W2242924685 @default.
- W2806366957 hasRelatedWork W2337109644 @default.
- W2806366957 hasRelatedWork W2806366957 @default.
- W2806366957 hasRelatedWork W2949911856 @default.
- W2806366957 hasRelatedWork W2951104772 @default.
- W2806366957 hasRelatedWork W4224589284 @default.
- W2806366957 hasVolume "37" @default.
- W2806366957 isParatext "false" @default.
- W2806366957 isRetracted "false" @default.
- W2806366957 magId "2806366957" @default.
- W2806366957 workType "article" @default.