FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2806374108> ?p ?o ?g. }

• W2806374108 endingPage "19678" @default.
• W2806374108 startingPage "19668" @default.
• W2806374108 abstract "The synthesis and characterization of bis(ketoiminato)magnesium(ii) complexes of composition [Mg(OCR2CH2CHR1NCH2CH2X)2] (X = NMe2: 3a, R1 = R2 = Me; 3b, R1 = Me, R2 = Ph. X = OMe: 3c, R1 = R2 = Me) are reported. Complexes 3a-c are accessible by the reaction of C(O)R2CH2CHR1N(H)CH2CH2X (X = NMe2: 1a, R1 = R2 = Me; 1b, R1 = Me, R2 = Ph. X = OMe: 1c, R1 = R2 = Me) with Mg n Bu2. The structure of 3b in the solid state was determined by a single crystal X-ray diffraction study, confirming that the Mg(ii) ion is hexa-coordinated by two ketoiminato ligands, while each of the latter coordinates with its two N- and one O-donor atom in an octahedral MgN6O2 coordination environment in the OC-6-33 stereo-isomeric form. The thermal behavior of 3a-c was studied by TG and DSC under an atmosphere of Ar and O2 respectively. The respective Me-substituted complexes 3a,c decompose at lower temperatures (3a, 166 °C; 3c, 233 °C) than the phenyl derivative 3b (243 °C). PXRD studies indicate the formation of MgO. Additionally, TG-MS studies were exemplarily carried out for 3a, indicating the release of the ketoiminato ligands. Vapor pressure measurements were conducted at 80 °C, whereby 3a,c possess with 5.6 mbar (3a) and 2.0 mbar (3c) significantly higher volatilities than 3b (0.07 mbar). Complexes 3a-c were used as MOCVD precursors for the deposition of thin MgO films on silicon substrates. It was found that only with 3a,c thin, dense and rather granulated MgO layers of thicknesses between 28-147 nm were produced. The as-deposited MgO layers were characterized by SEM, EDX, and XPS measurements and the thicknesses of the as-deposited layers were measured by Ellipsometry and SEM cross-section images. Apart from magnesium and oxygen a carbon content between 3-4 mol% was determined." @default.
• W2806374108 created "2018-06-13" @default.
• W2806374108 creator A5009515838 @default.
• W2806374108 creator A5035562384 @default.
• W2806374108 creator A5037147089 @default.
• W2806374108 creator A5039286027 @default.
• W2806374108 creator A5039877065 @default.
• W2806374108 creator A5047693293 @default.
• W2806374108 creator A5057479765 @default.
• W2806374108 creator A5076963256 @default.
• W2806374108 creator A5088576809 @default.
• W2806374108 creator A5090018109 @default.
• W2806374108 date "2018-01-01" @default.
• W2806374108 modified "2023-10-05" @default.
• W2806374108 title "Magnesium β-ketoiminates as CVD precursors for MgO formation" @default.
• W2806374108 cites W102925800 @default.
• W2806374108 cites W1914720887 @default.
• W2806374108 cites W1963796861 @default.
• W2806374108 cites W1966151474 @default.
• W2806374108 cites W1974414386 @default.
• W2806374108 cites W1980749958 @default.
• W2806374108 cites W1981325582 @default.
• W2806374108 cites W1981556134 @default.
• W2806374108 cites W1981836106 @default.
• W2806374108 cites W1986831986 @default.
• W2806374108 cites W1990373160 @default.
• W2806374108 cites W1992214743 @default.
• W2806374108 cites W1999162440 @default.
• W2806374108 cites W1999829102 @default.
• W2806374108 cites W2010100140 @default.
• W2806374108 cites W2011250053 @default.
• W2806374108 cites W2014624302 @default.
• W2806374108 cites W2016592109 @default.
• W2806374108 cites W2023266575 @default.
• W2806374108 cites W2039102013 @default.
• W2806374108 cites W2048003090 @default.
• W2806374108 cites W2059203317 @default.
• W2806374108 cites W2059966596 @default.
• W2806374108 cites W2067745168 @default.
• W2806374108 cites W2074600093 @default.
• W2806374108 cites W2078150144 @default.
• W2806374108 cites W2079367974 @default.
• W2806374108 cites W2087042959 @default.
• W2806374108 cites W2093474360 @default.
• W2806374108 cites W2102873070 @default.
• W2806374108 cites W2106414543 @default.
• W2806374108 cites W2107610028 @default.
• W2806374108 cites W2116527089 @default.
• W2806374108 cites W2131350133 @default.
• W2806374108 cites W2144508730 @default.
• W2806374108 cites W2158236037 @default.
• W2806374108 cites W2169145206 @default.
• W2806374108 cites W2173864775 @default.
• W2806374108 cites W2239373818 @default.
• W2806374108 cites W2320535011 @default.
• W2806374108 cites W2333660248 @default.
• W2806374108 cites W2466558606 @default.
• W2806374108 cites W2526161778 @default.
• W2806374108 cites W2563714720 @default.
• W2806374108 cites W2768002363 @default.
• W2806374108 cites W2773278271 @default.
• W2806374108 doi "https://doi.org/10.1039/c8ra01851k" @default.
• W2806374108 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/35540974" @default.
• W2806374108 hasPublicationYear "2018" @default.
• W2806374108 type Work @default.
• W2806374108 sameAs 2806374108 @default.
• W2806374108 citedByCount "10" @default.
• W2806374108 countsByYear W28063741082019 @default.
• W2806374108 countsByYear W28063741082020 @default.
• W2806374108 countsByYear W28063741082021 @default.
• W2806374108 countsByYear W28063741082022 @default.
• W2806374108 countsByYear W28063741082023 @default.
• W2806374108 crossrefType "journal-article" @default.
• W2806374108 hasAuthorship W2806374108A5009515838 @default.
• W2806374108 hasAuthorship W2806374108A5035562384 @default.
• W2806374108 hasAuthorship W2806374108A5037147089 @default.
• W2806374108 hasAuthorship W2806374108A5039286027 @default.
• W2806374108 hasAuthorship W2806374108A5039877065 @default.
• W2806374108 hasAuthorship W2806374108A5047693293 @default.
• W2806374108 hasAuthorship W2806374108A5057479765 @default.
• W2806374108 hasAuthorship W2806374108A5076963256 @default.
• W2806374108 hasAuthorship W2806374108A5088576809 @default.
• W2806374108 hasAuthorship W2806374108A5090018109 @default.
• W2806374108 hasBestOaLocation W28063741081 @default.
• W2806374108 hasConcept C110738630 @default.
• W2806374108 hasConcept C115624301 @default.
• W2806374108 hasConcept C175665537 @default.
• W2806374108 hasConcept C178790620 @default.
• W2806374108 hasConcept C185592680 @default.
• W2806374108 hasConcept C198819137 @default.
• W2806374108 hasConcept C2779227376 @default.
• W2806374108 hasConcept C543218039 @default.
• W2806374108 hasConcept C57410435 @default.
• W2806374108 hasConcept C73922627 @default.
• W2806374108 hasConcept C8010536 @default.
• W2806374108 hasConceptScore W2806374108C110738630 @default.
• W2806374108 hasConceptScore W2806374108C115624301 @default.
• W2806374108 hasConceptScore W2806374108C175665537 @default.

• next