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- W2806480012 abstract "Abstract We prepared a cationic indium catalyst for the conversion of epoxides and lactones into spiro‐orthoesters (SOEs), a family of expanding monomers. The cationic indium alkyl complexes [(NN i O)In(CH 2 SiMe 3 )(S)][B{3,5‐(CF 3 ) 2 C 6 H 3 } 4 ] ( 2⋅ Solv; H(NN i O)=2,4‐dicumyl‐6‐({[2‐(dimethylamino)cyclohexyl]imino}methyl)phenol, S=OEt 2 or THF) were synthesized and fully characterized. The reaction of ϵ‐caprolactone with 1,2‐epoxy‐7‐octene resulted in the formation of 2‐(hex‐5‐en‐1‐yl)‐1,4,6‐trioxaspiro[4.6]undecane (SOE1) with full conversion of both components. We extended the substrate scope to five‐ and six‐membered lactones as well as to a number of functionalized epoxides. The reactivity of the SOEs was explored." @default.
- W2806480012 created "2018-06-13" @default.
- W2806480012 creator A5008202977 @default.
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- W2806480012 creator A5075805507 @default.
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- W2806480012 date "2018-05-30" @default.
- W2806480012 modified "2023-10-14" @default.
- W2806480012 title "Coupling of Epoxides and Lactones by Cationic Indium Catalysts To Form Functionalized Spiro-Orthoesters" @default.
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- W2806480012 doi "https://doi.org/10.1002/cctc.201800474" @default.
- W2806480012 hasPublicationYear "2018" @default.