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• W2806524719 startingPage "14272" @default.
• W2806524719 abstract "Calcium borohydride, as a promising hydrogen storage material, has been investigated by synchrotron X-ray diffraction (XRD) and Raman spectroscopy upon compression in a diamond anvil cell. A pressure-induced phase transition is confirmed by XRD patterns and Raman spectra. The new phase matches the predicted isoenergetic structure with C2/c space group. In the process of phase transition, there is a wide region from 2.36 to 7.97 GPa in our XRD patterns, and the volume collapse is 3.86%. We have also carried out Raman spectroscopy up to 43.5 GPa, and the same phase transition is found at 3.59 GPa. Another initial phase γ-Ca(BH4)2 is stable, and the pressure-induced amorphization occurs above 13.8 GPa." @default.
• W2806524719 created "2018-06-13" @default.
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• W2806524719 date "2018-06-05" @default.
• W2806524719 modified "2023-10-17" @default.
• W2806524719 title "New Phase of Ca(BH₄)₂ at Near Ambient Conditions" @default.
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• W2806524719 doi "https://doi.org/10.1021/acs.jpcc.8b02196" @default.
• W2806524719 hasPublicationYear "2018" @default.
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