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- W2806530176 abstract "A new strategy, a transient homocoupling dimer strategy, for direct catalytic oxidative cross-enolate coupling reactions is developed. Cross-enolate coupling products bearing a (contiguous) tetrasubstituted carbon center were obtained chemoselectively without the need for stoichiometric amounts of strong bases/metal oxidants, and thus, the present catalysis provides a general method for the synthesis of unnatural α,α-disubstituted amino acid motifs. The distinct transformation of azlactone and 2-acylimidazole units highlighted the synthetic utility of the present catalysis." @default.
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- W2806530176 date "2018-05-31" @default.
- W2806530176 modified "2023-10-16" @default.
- W2806530176 title "Strategy for Catalytic Chemoselective Cross-Enolate Coupling Reaction via a Transient Homocoupling Dimer" @default.
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- W2806530176 doi "https://doi.org/10.1021/acs.orglett.8b01313" @default.
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