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- W2806535366 abstract "In this paper, potentiodynamic cathode polarization, chronopotentiometry and galvanostatic measurement (GM) are applied to obtain electrochemical property of three levelers (oligomers with different ratios of imidazole and 1,4-butanediol diglycidyl ether, named L1, L2 and L3, respectively) at different rotation speeds. Measured by GM with varied levelers, potential differences (PDs) are confirmed as effective indicators of THs plating and named △η (caused by self-inhibition of leveler) and △ηr (caused by different convection). The slope of the Tafel curve, obtained by chronopotentiometry, is a bridge to connect PDs to uniformity of THs plating. Also, the multi-physical coupling simulation based on the finite element method is introduced to investigate leveling effect on uniformity. A model based on Haring cell is formulated to predict the relationship between PDs and uniformity. Furthermore, numerical simulation and plating experiment both show that levelers with more negative PDs lead to more uniform conformal THs copper deposition and a systematic relationship between PDs and uniformity of THs plating is established. The weightings of △η and △ηr are also achieved for THs playing. Finally, the model paves an alternative way to screen for better leveler based on the relationship between PDs and uniformity of THs plating." @default.
- W2806535366 created "2018-06-13" @default.
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- W2806535366 date "2018-01-01" @default.
- W2806535366 modified "2023-09-29" @default.
- W2806535366 title "Electrochemical Factors of Levelers on Plating Uniformity of Through-Holes: Simulation and Experiments" @default.
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- W2806535366 doi "https://doi.org/10.1149/2.0331809jes" @default.
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