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- W2806574595 abstract "We report the synthesis of polyphosphazenes by a fast Staudinger reaction between a bis-PFAA (perfluoroaryl azide) and a bis-phospine. Polymerization was completed within 30 min after mixing the two monomers (20 mM) in CH3CN under ambient conditions to give polyphosphazene with molecular weight of up to over 59 000 and a narrow dispersity (Đ) of 1.1–1.2. This is a significant improvement over the polyphosphazenes obtained from the classic Staudinger reaction which had lower molecular weight (M̅n = 10 000–25 000) and higher Đ (1.7). This reaction applies to bis-PFAAs and bis-phosphines with either an aromatic or an aliphatic linker. Polarity of the solvent influenced the degree of polymerization, and more polar solvents such as acetonitrile gave higher molecular weight polymer in comparison to less polar solvents such as dichloromethane. The synthesized polyphosphazenes showed high thermal stability, with the aromatic polyphosphazenes giving decomposition temperature and char yield of up to of 441 °C and 53%, respectively." @default.
- W2806574595 created "2018-06-13" @default.
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- W2806574595 date "2018-06-07" @default.
- W2806574595 modified "2023-10-14" @default.
- W2806574595 title "Synthesis of Polyphosphazenes by a Fast Perfluoroaryl Azide-Mediated Staudinger Reaction" @default.
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- W2806574595 cites W1973575282 @default.
- W2806574595 cites W1975475423 @default.
- W2806574595 cites W1978702607 @default.
- W2806574595 cites W1979594095 @default.
- W2806574595 cites W1981316754 @default.
- W2806574595 cites W1988478118 @default.
- W2806574595 cites W1989561677 @default.
- W2806574595 cites W1998153355 @default.
- W2806574595 cites W2000950914 @default.
- W2806574595 cites W2003999024 @default.
- W2806574595 cites W2005634291 @default.
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- W2806574595 cites W2010477003 @default.
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- W2806574595 cites W2040631183 @default.
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- W2806574595 doi "https://doi.org/10.1021/acs.macromol.8b00618" @default.
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