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• W2806679660 abstract "A trigonal nanosized carboxylate ligand, 4, 4′,4″-(triazine-2,4,6-triyl-tris(benzene-4,1-diyl))tribenzoic acid (H3TAPB), has been applied in the construction of a highly porous metal−organic framework (MOF). A solvothermal reaction of H3TAPB and a zinc salt in a mixed solvent of DEF/dioxane/H2O produces the targeted porous MOF [Zn3(TAPB)2(H2O)2](DEF)4(H2O)3 (1, DEF = N,N-Diethylformamide). This MOF contains a linear Zn3 secondary building unit with two terminal water molecules occupied the axis positions, which is connected by the TAPB3− ligands to afford a 3-fold interpenetrated framework with a large calculated void volume (69.7%). The activated MOF shows exceptional porosities and high CO2 uptake capacities as well as good sorption selectivity of CO2/CH4 around room temperature." @default.
• W2806679660 created "2018-06-13" @default.
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• W2806679660 date "2018-08-01" @default.
• W2806679660 modified "2023-10-18" @default.
• W2806679660 title "A porous Zn-based metal-organic framework with an expanded tricarboxylic acid ligand for effective CO2 capture and CO2/CH4 separation" @default.
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• W2806679660 doi "https://doi.org/10.1016/j.inoche.2018.05.031" @default.
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