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• W2806884512 abstract "In this work, we studied the fragmentation dynamics of 2-deoxy-d-ribose (DR) in solution that arises from the double ionization of a water molecule in its primary hydration shell. This process was modeled in the framework of ab initio molecular dynamics. The charge unbalanced in the solvent molecules produces a Coulomb explosion with the consequent release of protons with kinetic energy in the few electronvolts range, which collide with the surrounding molecules in solution inducing further chemical reactions. In particular, we observe proton collisions with the solute molecule DR, which leads to a complete ring opening. In DNA, damage to the DR moiety may lead to DNA strand breaking. This mechanism can be understood as one of the possible steps in the radiation-induced fragmentation of DNA chains." @default.
• W2806884512 created "2018-06-13" @default.
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• W2806884512 date "2018-05-30" @default.
• W2806884512 modified "2023-10-10" @default.
• W2806884512 title "Proton Collision on Deoxyribose Originating from Doubly Ionized Water Molecule Dissociation" @default.
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• W2806884512 doi "https://doi.org/10.1021/acs.jpca.8b04787" @default.
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• W2806884512 hasPublicationYear "2018" @default.
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