Matches in SemOpenAlex for { <https://semopenalex.org/work/W2806987478> ?p ?o ?g. }
- W2806987478 endingPage "5993" @default.
- W2806987478 startingPage "5988" @default.
- W2806987478 abstract "Transformation of C5 furaldehydes to the corresponding C6 furaldehydes over a heterogeneous catalyst is a versatile but demanding reaction process. This report describes our discovery that Amberlyst-15, a conventional sulfuric functionalized resin, affords a 43.1% yield for 5-hydroxymethyl-2-furaldehyde (HMF) production with 57.5% selectivity via direct hydroxymethylation of 2-furaldehyde (furfural) with an aqueous formaldehyde reagent. This report is the first to describe an important achievement on the heterogeneous acid catalyst-assisted HMF production from furfural via direct hydroxymethylation in a batch reactor system. The Amberlyst-15 was also reusable and applicable for C5 furaldehyde upgrading of various types: furfuryl alcohol, furfurylamine, and furoic acid toward the corresponding C6 furaldehydes. Results show that a liquid flow system becomes an advanced tool for the continuous production of upgrading furaldehydes through a fixed Amberlyst-15 catalyst bed. Accordingly, the sulfuric functionalized resin-catalyzed direct hydroxymethylation of furaldehydes with aqueous formaldehyde in both batch and flow reactor systems is worthwhile and opens up new avenues for biomass transformations in particles, an important area of inedible biomass utilization." @default.
- W2806987478 created "2018-06-13" @default.
- W2806987478 creator A5009715855 @default.
- W2806987478 creator A5055648034 @default.
- W2806987478 creator A5076199173 @default.
- W2806987478 date "2018-06-04" @default.
- W2806987478 modified "2023-09-28" @default.
- W2806987478 title "Direct Hydroxymethylation of Furaldehydes with Aqueous Formaldehyde over a Reusable Sulfuric Functionalized Resin Catalyst" @default.
- W2806987478 cites W1147828101 @default.
- W2806987478 cites W1617660101 @default.
- W2806987478 cites W1830673052 @default.
- W2806987478 cites W1966551614 @default.
- W2806987478 cites W1970252081 @default.
- W2806987478 cites W1981986998 @default.
- W2806987478 cites W1982142271 @default.
- W2806987478 cites W1983841964 @default.
- W2806987478 cites W1994790185 @default.
- W2806987478 cites W1995426068 @default.
- W2806987478 cites W2001249953 @default.
- W2806987478 cites W2009271692 @default.
- W2806987478 cites W2016481574 @default.
- W2806987478 cites W2027584654 @default.
- W2806987478 cites W2042786605 @default.
- W2806987478 cites W2062467969 @default.
- W2806987478 cites W2066406750 @default.
- W2806987478 cites W2073509858 @default.
- W2806987478 cites W2074741255 @default.
- W2806987478 cites W2076266765 @default.
- W2806987478 cites W2098703212 @default.
- W2806987478 cites W2099786806 @default.
- W2806987478 cites W2102047281 @default.
- W2806987478 cites W2103876096 @default.
- W2806987478 cites W2106440266 @default.
- W2806987478 cites W2110100011 @default.
- W2806987478 cites W2143375710 @default.
- W2806987478 cites W2163156526 @default.
- W2806987478 cites W2164359477 @default.
- W2806987478 cites W2165032076 @default.
- W2806987478 cites W2167451090 @default.
- W2806987478 cites W2175816843 @default.
- W2806987478 cites W2317704676 @default.
- W2806987478 cites W2320346957 @default.
- W2806987478 cites W2322342266 @default.
- W2806987478 cites W2322896908 @default.
- W2806987478 cites W2325471132 @default.
- W2806987478 cites W2346359342 @default.
- W2806987478 cites W2346854887 @default.
- W2806987478 cites W2400525673 @default.
- W2806987478 cites W2463420066 @default.
- W2806987478 cites W2607374529 @default.
- W2806987478 cites W2610616754 @default.
- W2806987478 cites W2613698088 @default.
- W2806987478 cites W2739475012 @default.
- W2806987478 cites W2740532074 @default.
- W2806987478 doi "https://doi.org/10.1021/acsomega.8b00120" @default.
- W2806987478 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/6644732" @default.
- W2806987478 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/31458789" @default.
- W2806987478 hasPublicationYear "2018" @default.
- W2806987478 type Work @default.
- W2806987478 sameAs 2806987478 @default.
- W2806987478 citedByCount "19" @default.
- W2806987478 countsByYear W28069874782018 @default.
- W2806987478 countsByYear W28069874782019 @default.
- W2806987478 countsByYear W28069874782020 @default.
- W2806987478 countsByYear W28069874782021 @default.
- W2806987478 countsByYear W28069874782022 @default.
- W2806987478 countsByYear W28069874782023 @default.
- W2806987478 crossrefType "journal-article" @default.
- W2806987478 hasAuthorship W2806987478A5009715855 @default.
- W2806987478 hasAuthorship W2806987478A5055648034 @default.
- W2806987478 hasAuthorship W2806987478A5076199173 @default.
- W2806987478 hasBestOaLocation W28069874781 @default.
- W2806987478 hasConcept C134121241 @default.
- W2806987478 hasConcept C161790260 @default.
- W2806987478 hasConcept C178790620 @default.
- W2806987478 hasConcept C184651966 @default.
- W2806987478 hasConcept C185592680 @default.
- W2806987478 hasConcept C191897082 @default.
- W2806987478 hasConcept C192562407 @default.
- W2806987478 hasConcept C2775930285 @default.
- W2806987478 hasConcept C2778199549 @default.
- W2806987478 hasConcept C2779719330 @default.
- W2806987478 hasConcept C2780526948 @default.
- W2806987478 hasConcept C40875361 @default.
- W2806987478 hasConceptScore W2806987478C134121241 @default.
- W2806987478 hasConceptScore W2806987478C161790260 @default.
- W2806987478 hasConceptScore W2806987478C178790620 @default.
- W2806987478 hasConceptScore W2806987478C184651966 @default.
- W2806987478 hasConceptScore W2806987478C185592680 @default.
- W2806987478 hasConceptScore W2806987478C191897082 @default.
- W2806987478 hasConceptScore W2806987478C192562407 @default.
- W2806987478 hasConceptScore W2806987478C2775930285 @default.
- W2806987478 hasConceptScore W2806987478C2778199549 @default.
- W2806987478 hasConceptScore W2806987478C2779719330 @default.
- W2806987478 hasConceptScore W2806987478C2780526948 @default.
- W2806987478 hasConceptScore W2806987478C40875361 @default.
- W2806987478 hasFunder F4320334764 @default.
- W2806987478 hasIssue "6" @default.