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• W2807002507 abstract "Abstract Metal–metal cooperation is integral to the function of many enzymes and materials, and model complexes hold enormous potential for providing insights into the capabilities of analogous multimetallic cores. However, the selective synthesis of heterobimetallic complexes still presents a significant challenge, especially for systems that hold the metals in close proximity and feature open or reactive coordination sites for both metals. To address this issue, a rigid, naphthyridine‐based dinucleating ligand featuring distinct binding environments was synthesized. This ligand enables the selective synthesis of a series of M II Cu I bimetallic complexes (M=Mn, Fe, Co, Ni, Cu, Zn), in which each metal center exclusively occupies its preferred binding pocket, from simple chloride salts. The precision of this selectivity is evident from cyclic voltammetry, ESI‐MS and anomalous X‐ray diffraction measurements." @default.
• W2807002507 created "2018-06-13" @default.
• W2807002507 creator A5071739723 @default.
• W2807002507 creator A5079726681 @default.
• W2807002507 date "2018-06-28" @default.
• W2807002507 modified "2023-10-03" @default.
• W2807002507 title "Selective Synthesis of a Series of Isostructural M ^II Cu ^I Heterobimetallic Complexes Spontaneously Assembled by an Unsymmetrical Naphthyridine‐Based Ligand" @default.
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• W2807002507 doi "https://doi.org/10.1002/chem.201802623" @default.
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