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• W2807286138 abstract "We report a new formal oxidation state for neptunium in a crystallographically characterizable molecular complex, namely Np2+ in [K(crypt)][NpIICp″3] [crypt = 2.2.2-cryptand, Cp″ = C5H3(SiMe3)2]. Density functional theory calculations indicate that the ground state electronic configuration of the Np2+ ion in the complex is 5f46d1." @default.
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• W2807286138 date "2018-06-05" @default.
• W2807286138 modified "2023-10-18" @default.
• W2807286138 title "Identification of the Formal +2 Oxidation State of Neptunium: Synthesis and Structural Characterization of {Np^II[C₅H₃(SiMe₃)₂]₃}^1–" @default.
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• W2807286138 doi "https://doi.org/10.1021/jacs.8b03907" @default.
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