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- W2807315937 abstract "Abstract The poly(ethylene-co-vinyl alcohol) (EVOH) ultrafiltration membrane is prepared via pre-evaporation combined thermally induced phase separation (TIPS), using a novel co-solvent that is a mixture of sulfolane and 1,3-propanediol. The porous surface is mainly caused by the low cooling rate of pre-evaporation stage. Based on the shorter pre-evaporation time, the evaporation of 1,3-propanediol provides a foundation for asymmetric structure. Subsequently, the quenching effect of water bath forms a dense layer below the porous surface. The compact degree of dense layer increases first and then decreases with the increase of pre-evaporation time (τ) or pre-evaporation temperature (T) or the mass fraction of 1,3-propanediol in co-solvent (β). Therefore, the rejection of bovine serum albumin (BSA) increases first and then decreases as τ or T or β increases. Meanwhile, the connectivity of membrane structure can also be adjusted by changing β. Finally, the EVOH ultrafiltration membrane prepared from τ = 20 s, T = 25 °C and β = 15% achieves relatively high BSA rejection of 98% and relatively large pure water flux of 302 L m−2 h−1 bar−1." @default.
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- W2807315937 date "2018-10-01" @default.
- W2807315937 modified "2023-09-27" @default.
- W2807315937 title "The role of pre-evaporation in the preparation process of EVOH ultrafiltration membranes via TIPS" @default.
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- W2807315937 doi "https://doi.org/10.1016/j.memsci.2018.06.003" @default.
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